78086-67-6

Upstream product

• 6752-49-4 (4aR,6S,8aR)-6-Methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-one 
• 74-88-4 methyl iodide 
• 63598-31-2 methyl 4,6-O-(R)-benzylidene-2-deoxy-α-D-erythrohexopyranosid-3-ulose 
• 917-54-4 methyllithium 
• 917-64-6 methyl magnesium iodide 
• 75-16-1 methylmagnesium bromide 
• 6752-49-4 (2R,6S)-6-Methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-one 
• 78013-74-8 1,5-Anhydro-4,6-O-benzyliden-2-desoxy-3-C-methyl-D-ribo-hex-1-enit 
• 66183-24-2 1,5-anhydro-4,6-O-benzylidene-2-deoxy-D-erythro-hex-3-ulo-1-enitol 

Downstream Products

• 74995-84-9 methyl 4-O-benzoyl-6-bromo-2,6-dideoxy-3-C-methyl-α-D-ribo-hexopyranoside 
• 74995-88-3 Methyl-2,3,4,6-tetradesoxy-3-C-methyl-4-thiophenyl-α-D-threo-hex-2-enopyranosid 
• 74995-89-4 Methyl-2,3,4,6-tetradesoxy-3-C-methyl-4-(phenylsulfinyl)-α-D-threo-hex-2-enopyranosid 
• 74995-86-1 Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranosid 
• 74995-92-9 Methyl-2-O-acetyl-4,6-didesoxy-3-C-methyl-4-(p-tolylsulfonylamino)-α-D-altropyranosid 
• 74995-85-0 Methyl-4-O-benzoyl-2,6-didesoxy-3-C-methyl-α-D-ribo-hexopyranosid 
• 78013-85-1 Methyl-4,6-didesoxy-3-C-methyl-4-(p-tolylsulfonylamino)-α-D-altropyranosid 
• 78013-83-9 Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methylen-α-D-erythro-hexopyranosid 
• 78013-86-2 Methyl-4,6-didesoxy-3-C-methyl-N-methyl-4-(p-tolylsulfonylamino)-α-D-altropyranosid 
• 100164-80-5 Methyl-3-O-acetyl-4,6-O-benzyliden-2-desoxy-3-C-methyl-α-D-ribo-hexopyranosid 
• 114244-33-6 (2R,3R,4S)-4-benzyloxy-4-methyl-1,2,3,6-hexanetetrol 
• 114244-31-4 1,4,6-tri-O-acetyl-3-O-benzyl-2-deoxy-3-C-methyl-β-D-ribo-hexopyranose 
• 114244-26-7 methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-3-C-methyl-α-D-ribo-hexopyranoside 

Relevant academic research and scientific papers

Isolation and structure elucidation of vicenistatin M, and importance of the vicenisamine aminosugar for exerting cytotoxicity of vicenistatin

A new analogue of vicenistatin was isolated from the producing strain Streptomyces sp. HC-34. A characteristic of the elucidated structure involved the existence of a neutral sugar mycarose instead of an aminosugar vicenisamine of vicenistatin. The absolu

Effect of nitrogen substitution on the diastereoselection of intramolecular nitrone/alkene cycloadditions

The diastereomeric ratios of several intramolecular nitrone/alkene cycloaddition reactions have been shown to be sensitive to the substituent on the nitrone nitrogen in a double diastereodifferentiation process.

Stereospezifische Darstellung C-methylverzweigter Kohlenhydrate mit Tetramethylzirkonium(IV)

Branched glycals and glycosides containing an HO-C-CH3 group were obtained stereospecifically by the action of tetramethylzirconium(IV), upon either α,β-unsatured enuloses or pyranosiduloses.L-Olivomycal and the C-4 epimer of L-mycaral were obtained from

Syntheses and Reactions of 3-C-Methyl-branched Glycals of the D-Series. Preparations of the Isomers of Terminal Disaccharides in Olivomycin A and Mithramycin

Syntheses of D-olivomycal (6) and D-mycaral (9) are achieved starting with D-rhamnal (4) or D-digitoxal (5), respectively.The transformation of 9 to methyl α-D-mycaroside (12) represents a configurational assignment at the branching point.With methyllithi

Synthesen biologisch wichtiger Kohlenhydrate, 24. Derivate des Sibirosamins (4,6-Didesoxy-3-C-methyl-4-methylamino-D-altropyranose) durch 4 -> 2-Chiralitaetstransfer und vic. cis-Oxyaminierung eines 3-C-Methyl-hex-3-enopyranosids

Methyl 4-O-benzoyl-2,6-didesoxy-3-C-methyl-α-D-ribo-hexopyranoside (14) yields the D-erythro configurated 3-C-branched hex-2-enopyranosides 15 and 16, resp., with high selectivity by elimination with thionyl chloride. 16 is transformed with complete inver