75072-04-7Relevant academic research and scientific papers
A family of highly stable lanthanide metal-organic frameworks: Structural evolution and catalytic activity
Gustafsson, Mikaela,Bartoszewicz, Agnieszka,Martiin-Matute, Belein,Sun, Junliang,Grins, Jekabs,Zhao, Tony,Li, Zhongyue,Zhu, Guangshan,Zou, Xiaodong
, p. 3316 - 3322 (2010)
A family of homeotypic porous lanthanide metal-organic frameworks (MOFs), [Ln(btc)(H2O)]·guest (Nd (1), Sm (2), Eu (3), Gd (4), Tb (5), Ho (6), Er (7), and Yb (8); guest: DMF or H2O) was synthesized. The structures of the as-synthesi
Synthesis of cyanooxovanadate and cyanosilylation of ketones
Hayashi, Yoshihito,Kawabata, Hiroko,Kikukawa, Yuji
, p. 31688 - 31692 (2021/11/30)
The cyanosilylation was performed by using metavanadate catalysts, and in situ measurements revealed the formation of [VO2(CN)3]2- and [VO4TMS2]- under reaction conditions. The reaction of [VO2(CN)3]2-, trimethylsilyl cyanide (TMSCN), and water afforded [
Pickering emulsion droplets hosting ionic liquid catalysts for continuous-flow cyanosilylation reaction
Meng, Zhixin,Zhang, Ming,Yang, Hengquan
supporting information, p. 627 - 633 (2019/02/14)
An IL-catalyzed cyanosilylation reaction is an important route for synthesis of many fine chemicals, but it is currently conducted in a batch manner. Herein, we have developed a novel method to "immobilize" IL catalysts for continuous-flow reaction based
Beyond Hydrofunctionalisation: A Well-Defined Calcium Compound Catalysed Mild and Efficient Carbonyl Cyanosilylation
Yadav, Sandeep,Dixit, Ruchi,Vanka, Kumar,Sen, Sakya S.
supporting information, p. 1269 - 1273 (2018/02/06)
Organocalcium compounds have been reported as efficient catalysts for various transformations, for cases in which one of the substrates contained an E?H (E=B, N, Si, P) bond. Here, we look at the possibility of employing an organocalcium compound for a tr
Lewis Acid Rather than Bronsted Acid Sites of Montmorillonite K10 Act as a Powerful and Reusable Green Heterogeneous Catalyst for Rapid Cyanosilylation of Ketones
Huang, Xiao,Chen, Lin,Ren, Fengying,Yang, Chen,Li, Jianghong,Shi, Kejin,Gou, Xiaojun,Wang, Wei
, p. 439 - 444 (2017/02/24)
A practical green protocol was developed for highly efficient cyanosilylation of various ketones catalyzed by commercial montmorillonite K10, with excellent isolated yields (91-99%). The catalyst can be used as received, and its catalytic strength can be
Porous barium-organic frameworks with highly efficient catalytic capacity and fluorescence sensing ability
Liu, Fuling,Xu, Yuwen,Zhao, Lianming,Zhang, Liangliang,Guo, Wenyue,Wang, Rongming,Sun, Daofeng
supporting information, p. 21545 - 21552 (2015/11/10)
The current study describes the first barium-organic framework with permanent porosity, efficient catalytic capacity, and highly selective luminescence sensing of DMSO molecules and metal ions. Single-crystal-to-single-crystal transformations (from comple
Efficient, rapid and solvent-free cyanosilylation of aldehydes and ketones catalyzed by SbCl3
Pourmousavi,Salahshornia
experimental part, p. 1575 - 1578 (2011/12/15)
Antimony trichloride(SbCl3) was demonstrated to be an effective catalyst for the cyanosilylation of a wide variety of carbonyl compounds under solvent-free conditions. The reactions proceeded smoothly at room temperature to afford the correspon
A dream combination for catalysis: Highly reactive and recyclable scandium(iii) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid
Park, Boyoung Y.,Ryu, Ka Yeon,Park, Jung Hwan,Lee, Sang-Gi
experimental part, p. 946 - 948 (2010/04/23)
The catalytic activity of lanthanide triflates, particularly scandium triflate, increased dramatically in [bmim][SbF6], allowing the cyanosilylation of a variety of aldehydes and ketones with a turnover frequency up to 48000 mol h-1 and a total turnover number of 100000.
Highly efficient cyanosilylation of sterically bulky ketones catalyzed by tin ion-exchanged montmorillonite
Wang, Jiacheng,Masui, Yoichi,Watanabe, Kenya,Onaka, Makoto
supporting information; experimental part, p. 553 - 557 (2009/10/25)
Tin ion-exchanged montmorillonite (SnMont) was found to be a powerful catalyst for the cyanosilylation of aromatic and aliphatic ketones having a carbonyl group in sterically congested circumstances with cyanotrimethylsilane, giving the corresponding cyan
Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient catalysts for the cyanosilylation and cyanocarbonation of aldehydes and ketones
Matsukawa, Satoru,Sekine, Izumi,Iitsuka, Ayumi
experimental part, p. 3353 - 3359 (2009/12/26)
A variety of aldehydes and ketones were transformed to their corresponding cyanohydrin silyl ethers in good to excellent yields in the presence of 1-5 mol% of tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP). Cyanohydrin carbonates were also readily prepared using 5-10 mol% of TTMPP as an organocatalyst.
