75140-69-1Relevant academic research and scientific papers
Copper-catalyzed 1,4-addition of organoboronates to alkylidene cyanoacetates: Mechanistic insight and application to asymmetric catalysis
Takatsu, Keishi,Shintani, Ryo,Hayashi, Tamio
supporting information; experimental part, p. 5548 - 5552 (2011/07/30)
In addition: A copper/N-heterocyclic carbene(NHC)-catalyzed 1,4-addition of organoboronates to alkylidene cyanoacetates was developed, in which the catalytic cycle is proposed to consist of a transmetalation/insertion/ligand exchange. An effective asymmetric variant has also been achieved by the use of a chiral NHC ligand (see scheme). Copyright
