75219-18-0

Upstream product

• 149-30-4 2-Mercaptobenzothiazole 
• 70-11-1 α-bromoacetophenone 
• 96-09-3 styrene oxide 
• 13944-95-1 2-(phenacylsulfanyl)-1,3-benzothiazole 
• 100-52-7 benzaldehyde 
• 106296-62-2 2-benzothiazol-2-ylthio(trimethylsilyl)ethanol 

Downstream Products

• 100-42-5 styrene 
• 2034-28-8 1-(4-methoxyphenyl)-5-phenyl-1H-[1,2,3]-triazole 
• 4874-85-5 1,5-diphenyl-1H-1,2,3-triazole 
• 156049-96-6 C₁₅H₁₁NO₂S₂ 
• 1009089-58-0 1-octyl-5-phenyl-1H-[1,2,3]triazole 
• 1350896-29-5 2-(benzo[d]thiazol-2-ylsulfonyl)-1-phenylethan-1-ol 
• 934-34-9 2-hydroxybenzothiazole 
• 1498-99-3 styrenesulfide 

Relevant academic research and scientific papers

Esterase-sensitive sulfur dioxide prodrugs inspired by modified Julia olefination

Sulfur dioxide (SO2) is an endogenously produced gaseous molecule, and is emerging as a potential gasotransmitter. Herein, we describe the first series of esterase-sensitive prodrugs inspired by modified Julia olefination as SO2 donors.

A metal-free, aqueous and general route to 1,5-disubstituted-1,2,3- triazoles: "Reversed regioisomeric" 1,3-dipolar cycloaddition of azides and vinyl sulfones

A metal-free, vinyl sulfone-based synthesis of 1,5-disubstituted-1,2,3- triazoles is reported for the first time. These triazoles are easily formed in a regioselective fashion by heating under reflux a mixture of a substituted vinyl sulfone and an organic

Thermolysis of β-hydroxysulfides bearing several heteroaromatics

Thermolyses of β-hydroxysulfides 2, bearing groups, such as 2-benzothiazolyl and 4-(4-methyl)-4H-1,2,4-triazolyl groups, were studied and found to afford the corresponding substituted styrenes 5 and hydroxy heteroaromatics in good yields, respectively. The product distribution change in the course of the thermolysis of 2a was also studied. The olefin products 5a were considered to be formed by the thermal desulfurization of the corresponding thiiranes 4a initially formed via the five-membered spiro intermediate 6a.

Reaction products of mercaptobenzothiazoles, mercaptothiazolines, and mercaptobenzimidazoles with epoxides as lubricant additives

A composition is disclosed that comprises: (A) a lubricant, and (B) at least one compound selected from the group consisting of alcohols of the formulae: wherein Y is N, O, or S; R1, R2, R3, and R4 are independe

Baker's yeast-induced asymmetric reduction of α-ketosulfides: Synthesis of optically active 1-(benzothiazol-2-ylsulfanyl)-2- alkanols, 2-alkanols, and thiiranes

1-(Benzothiazol-2-ylsulfanyl)-2-alkanols 3 were prepared in very high enantiomeric excess by baker's yeast-induced asymmetric reduction of 1- (benzothiazol-2-ylsulfanyl)-2-alkanones 1. Conversion of 3 into optically active simple 2-alkanols 4 and thiiranes 2 by reductive desulfurization and base treatment, respectively, is also described. The absolute configuration of the new compounds synthesized has been established by chemical correlation and specific rotation comparison.

PREPARATION OF NEW THIOCARBANION SPECIES BEARING THIAZOLINYL AND BENZOTHIAZOLYL GROUPS AND REACTIONS WITH CARBONYL COMPOUNDS

2-Trimethylsilylmethylthiothiazoline (1) reacted with aromatic aldehydes in the presence of cesium fluoride or tris(dimethylamino)sulfur(trimethylsilyl)difluoride (TASF) to give 2-heteroarylthioethanol (4) or thiiran (5) derivatives in good yields.The rea