75269-57-7

Upstream product

• 827-15-6 1,2,3,4,5-pentafluoro-6-iodobenzene 
• 24973-40-8 pentafluorophenyliodine dinitrate 
• 14353-88-9 iodopentafluorobenzene bis(trifluoroacetate) 
• 24973-39-5 pentafluoro(difluoroiodo)benzene 
• 14353-90-3 1,2,3,4,5-pentafluoro-6-iodosylbenzene 
• 363-72-4 Pentafluorobenzene 
• 38091-68-8 Pentafluorophenyliodine tetrafluoride 
• 75269-58-8 pentafluorophenyliodine dioxide 

Downstream Products

• 75284-38-7 μ-oxotetrakis(pentafluorophenyl)diiodine(V) dioxide 
• 75269-58-8 pentafluorophenyliodine dioxide 

Relevant academic research and scientific papers

Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride, Part 2. Electrophilic oxygenation of pentafluorobenzene derivatives C6F5X

Electrophilic oxygenation of polyfluorobenzenes C6F5X (X = F, Cl, Br, H, CF3, NH3+, NMe3+, OH and OCH2CF3) with XeF2 and H2O in HF leads to the formation of polyfluorinated 1,4-cyclohexadienones. Pentafluoroiodobenzene is converted into C6F5IF2 and C6F5IF4, whereas [C6F5N2]+ [NbF6]- is unreactive towards this new type of electrophilic oxygenation.

Aromatic fluorine derivatives LXXXVI. Direct introduction of pentavalent iodine into fluorine-containing benzenes. Generation of pentafluorophenyltrifluoroiodonium ion

The reaction of 1,3,5-trifluorobenzene and pentafluorobenzene with IF4SbFnCl6-n led to the formation of compounds the hydrolysis of which gave fluorinated aromatic derivatives of pentavalent iodine.The fluorine-containing aryliodonium ion C6H5IF3+ was generated for the first time, and its structure and characteristics were compared with those of other known heteroanalogs of perfluorinated benzyl cations.