75284-38-7Relevant academic research and scientific papers
Aromatic fluorine derivatives LXXXVI. Direct introduction of pentavalent iodine into fluorine-containing benzenes. Generation of pentafluorophenyltrifluoroiodonium ion
Bardin, V. V.,Furin, G. G.,Yakobson, G. G.
, p. 1086 - 1092 (2007/10/02)
The reaction of 1,3,5-trifluorobenzene and pentafluorobenzene with IF4SbFnCl6-n led to the formation of compounds the hydrolysis of which gave fluorinated aromatic derivatives of pentavalent iodine.The fluorine-containing aryliodonium ion C6H5IF3+ was generated for the first time, and its structure and characteristics were compared with those of other known heteroanalogs of perfluorinated benzyl cations.
AROMATIC FLUORINE DERIVATIVES LXXXVII. GENERATION OF PENTAFLUOROPHENYLFLUOROIODONIUM ION
Bardin, V. V.,Furin, G. G.,Yakobson, G. G.
, p. 1288 - 1291 (2007/10/02)
The pentafluoroiodonium ion C6F5IF+ was generated by the action of antimony pentafluoride on pentafluorophenyliodine difluoride at -30 deg.C.For the case of the reaction with pentafluorobenzene it was shown that this cation is a stronger electrophilic agent than previously known iodonium salts RR'I+.Under the influence of fluorosulfonic acid iodosylpentafluorobenzene probably forms a complex of the donor-acceptor type.
