75337-98-3Relevant academic research and scientific papers
STEREOCONTROLLED TOTAL SYNTHESIS OF (+)-PEDERINE
Matsuda, Fuyuhiko,Tomiyoshi, Nobuya,Yanagiya, Mitsutoshi,Matsumoto, Takeshi
, p. 7063 - 7080 (2007/10/02)
A mild one-pot method for the synthesis of acyclic N-(1-methoxyalkyl)amides starting from carboxylic acid and methyl imidates has been developed and applied to the first total synthesis of (+)-pederine (1), a potent insect poison.Furthermore, the stereocontrolled total synthesis of 1 was also achieved by employing acid catalyzed double alkoxy-exchange reaction of N-(1-methoxyalkyl)amide group as key step.
TOTAL SYNTHESIS OF (+)-PEDERINE. A SIMPLE SYNTHETIC METHOD FOR N-(1-METHOXYALKYL)AMIDES
Matsuda, Fuyuhiko,Yanagiya, Mitsutoshi,Matsumoto, Takeshi
, p. 4043 - 4046 (2007/10/02)
A mild one-pot method for the synthesis of acyclic N-(1-methoxyalkyl)amides starting from carboxylic acids and methyl imidates had been developed and applied to the total synthesis of the insect poison pederine 1.
