75366-42-6Relevant articles and documents
Chelation-controlled 1,3-asymmetric induction in radical addition to γ- hydroxy- and γ-alkoxy-α-methylenecarboxylic esters
Nagano, Hajime,Toi, Satoko,Yajima, Tomoko
, p. 53 - 54 (1999)
The radical-mediated reactions of γ-hydroxy- and γ-alkoxy-α- methylenecarboxylic esters 3 (R1 = Ph, i-Bu, and t-Bu, R2 = H, Me, MOM, and MEM) with isopropyl iodide or cyclohexyl iodide performed in the presence of Lewis acids gave the syn-adducts 4 predominantly, whereas the anti-adduct 5 was the major product in the reaction of 3 (R1 = Ph, R2 = Me) with t-butyl iodide.
2-ALKOXYCARBONYLALLYLTRIMETHYLSILANES AS NEW REAGENTS OF 2-ALKOXYCARBONYLALLYLATION OF ELECTROPHILES
Hosomi, Akira,Hashimoto, Hidehiko,Sakurai, Hideki
, p. 951 - 954 (2007/10/02)
2-Alkoxycarbonylallylsilanes are useful for 2-alkoxycarbonylallylation of acetals and carbonyl compounds with an aid of a Lewis acid; the products can be readily converted to α-methylene-γ-butyrolactones.
