17962-38-8 Usage
General Description
DIETHYL(TRIMETHYLSILYLMETHYL)MALONATE is a chemical compound with the molecular formula C12H26O4Si. It is a colorless liquid with a fruity odor, commonly used as a reagent in organic synthesis. DIETHYL(TRIMETHYLSILYLMETHYL)MALONATE is a derivative of malonic acid and contains a trimethylsilyl-protected methyl group, making it a useful precursor for the synthesis of various organic compounds. It is also used as a cross-coupling reagent in organic reactions, particularly in the formation of carbon-carbon bonds. Additionally, it serves as a building block for the synthesis of complex molecules with pharmaceutical and agricultural applications. Overall, DIETHYL(TRIMETHYLSILYLMETHYL)MALONATE is a versatile and important chemical in the field of organic chemistry.
Check Digit Verification of cas no
The CAS Registry Mumber 17962-38-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,9,6 and 2 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 17962-38:
(7*1)+(6*7)+(5*9)+(4*6)+(3*2)+(2*3)+(1*8)=138
138 % 10 = 8
So 17962-38-8 is a valid CAS Registry Number.
InChI:InChI=1/C7H10N2/c1-2-3-7-6-8-4-5-9-7/h4-6H,2-3H2,1H3
17962-38-8Relevant articles and documents
Synthesis of rac-2′-(trimethylsilyl)isovaline: A novel silicon-containing α,α-dialkylated α-amino acid
Falgner, Steffen,Buchner, Ginka,Tacke, Reinhold
, p. 2614 - 2617 (2010)
An efficient, convenient, and reliable multi-step synthesis of rac-2′-(trimethylsilyl)isovaline (rac-3) that uses inexpensive reagents in all steps has been developed, starting from diethyl malonate (overall yield 28%). Compound rac-3 is the first α-ethyl
2-ALKOXYCARBONYLALLYLTRIMETHYLSILANES AS NEW REAGENTS OF 2-ALKOXYCARBONYLALLYLATION OF ELECTROPHILES
Hosomi, Akira,Hashimoto, Hidehiko,Sakurai, Hideki
, p. 951 - 954 (2007/10/02)
2-Alkoxycarbonylallylsilanes are useful for 2-alkoxycarbonylallylation of acetals and carbonyl compounds with an aid of a Lewis acid; the products can be readily converted to α-methylene-γ-butyrolactones.
