75392-03-9Relevant academic research and scientific papers
Thermodynamic characteristics of triphenylantimony bis(acetophenoneoximate)
Markin,Letyanina,Smirnova,Sharutin,Molokova
, p. 1315 - 1321 (2011)
The temperature dependence of heat capacity C p ° = f(T) of triphenylantimony bis(acetophenoneoximate) Ph3Sb(ONCPhMe) 2 was measured for the first time in an adiabatic vacuum calorimeter in the range of 6.5-370
Standard thermochemical characteristics of formation of triphenylantimony bis(acetophenoneoximate)
Markin,Letyanina,Smirnova,Sharutin,Molokova
, p. 1499 - 1502 (2013/02/25)
For the first time, the energy of combustion Δc U of crystalline triphenylantimony bis(acetophenoneoximate) Ph3Sb(ONCPhMe) 2 has been measured at T = 298.15 K using the isothermal combustion calorimeter with a stationary b
Synthesis and structures of triphenylantimony oximates
Dodonov,Gushchin,Gor'Kaev,Fukin,Starostina,Zakharov,Kurskii,Shavyrin
, p. 1051 - 1057 (2007/10/03)
The reactions of triphenylantimony or trimethylantimony with tert-butyl hydroperoxide in the presence of acetone oxime, acetophenone oxime, cyclohexanone oxime, or benzaldehyde oxime afforded monomeric triorganoantimony oximates Ph3Sb(ON=CMesu
Synthesis and structure of triphenylantimony bis(acetophenoneoximate)
Sharutin,Sharutina,Molokova,Pakusina,Gerasimenko,Gerasimenko
, p. 464 - 467 (2008/10/08)
Triphenylantimony bis(acetophenoneoximate) was synthesized by the reaction of triphenylantimony with hydrogen peroxide in the presence of acetophenone oxime (taken in the molar ratio of 1:1:2) in ether. The structure of the obtained compound was determined by X-ray diffraction. The Sb atom has a distorted trigonal-bipyramidal coordination with the oxime groups in the axial positions. The Sb-C(Ph)eq bond lengths are 2.110(1)-2.113(1) A, and the Sb-O distances are 2.058(1) and 2.067(1) A. The intramolecular Sb(1)...N(1, 2) contacts and O(1)SbO(2) axial angle are 2.990(1), 2.916(1) A and 172.49(4)°, respectively.
Synthesis and Spectral Studies of Triphenylantimony(V) Oximates and Benzamidoximate
Jain, V. K.,Bohra, R.,Mehrotra, R. C.
, p. 408 - 410 (2007/10/02)
Complexes of the general formula, Ph3Sb(ONCRR')2 (where R and R'=Me,Me; Me,Et; Me,Pr; Me,Ph; Et,Et; Et,Pr and NH2,Ph), have been synthesised and characterised.A trigonal bipyramidal geometry has been suggested for these complexes.They can be purified by recrystallization and on distillation under reduced pressure, they yield triphenylantimony.
