75420-45-0

Upstream product

• 54716-03-9 3-methylpenta-2(Z),4-dien-1-al 
• 40930-20-9 (2Z)-3-methylpenta-2,4-dien-1-ol 
• 1572-08-3 (E)-3-methylpenta-2,4-dien-1-ol 
• 6153-05-5 (Z)-3-methylpent-2-en-4-ynol 
• 6153-06-6 (E)-3-methylpent-2-en-4-yn-1-ol 
• 20459-97-6 3-Methyl-4-pentensaeure-methylester 
• 20425-55-2 (R)-(+)-6-acetoxy-4-methylhexanoic acid 
• 502164-45-6 2,2-dimethyl-3-((S)-3-methylpent-4-enyl)oxirane 
• 2436-90-0 (S)-(+)-dihydromyrcene 
• 80654-40-6 methyl (R)-3-methyl-5-o-nitrophenylselenopentanoate 
• 80654-41-7 (R)-3-methyl-5-o-nitrophenylselenopentanoic acid 
• 67-56-1 methanol 
• 64234-27-1 ((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane 
• 220131-44-2 1,1,4-trimethyl-1,2,3,6-tetrahydro-siline 

Downstream Products

• 22460-59-9 (3R/S,6S)-2,6-dimethyl-1,7-octadien-3-ol 
• 54702-01-1 (S)-2,6,6-Trimethyl-1-(3-methyl-pent-4-enyl)-cyclohexa-2,4-dienol 

Relevant academic research and scientific papers

A ring-closing metathesis approach to cyclic α,β-dehydroamino acids

A comprehensive study on the synthesis and ring-closing metathesis (RCM) of α,β-dehydroamino acids is described. This sequence has led to the formation of a range of biologically relevant functionalized nitrogen heterocycles. The incorporation of chiral b

Silacycles as templates for acyclic diastereoselection

The 4-substituted silacyclohex-3-enes (3) prepared from the vinyl triflate (9) derived from 1,1-dimethyl-1-silacyclohexan-4-one (1) and higher- order organocuprates provides a versatile template for the construction of non-racemic 3-methyl-4-penten-1-ol (6). Through asymmetric hydroboration, 3 affords the requisite β-hydroxysilane (4) with the idea/geometry to undergo elimination to the chiral acyclic silane (5) which is oxidatively converted to 6.

REGIO- AND STEREOSELECTIVE HYDROGENATION OF METHYL SUBSTITUTED PENTADIEN-1-OLS BY BAKER'S YEAST

(E)-2-methyl and (E)-3-methyl-2,4-pentadien-1-ols are reduced to (S)-2-methyl- and (S)-3-methyl-4-penten-1-ols, respectively, using baker's yeast as a regio- and stereoselective reagent.This microbiological conversion provides an efficient route to bifunctional and enantiomerically pure C6-building blocks containing the C'-CH(Me)-C'' grouping.

A Stereocontrolled Access to (+/-)-, (-)-, and (+)-Patchouli Alcohol

The racemate and both enantiomers of patchouli alcohol have been synthesized by stereocontrolled routes.The olfactive properties of the alcohols prepared are reported.

Stereoselective Synthesis of (S,E)-6-Isopropyl-3,9-dimethyl-5,8-decadienyl Acetate, the (S)-Enantiomer of the Yellow Scale Pheromone

The (S)-enantiomer of the sex pheromone of the yellow scale (Aonidiella citrina), (S,E)-6-isopropyl-3,9-dimethyl-5,8-decadienyl acetate, was stereoselectively synthesized from (R)-(+)-citronellic acid.