75455-74-2

Upstream product

• 14898-67-0 ruthenium(III) chloride trihydrate 
• 603-32-7 triphenyl-arsane 
• 50-00-0 formaldehyd 
• 10049-08-8 ruthenium(III)chloride 

Downstream Products

• 75455-77-5 RuH(CO)2Cl(As(C₆H₅)3)2 
• 131931-11-8 RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2⁽¹⁺⁾*B(C₆H₅)4^(1-)=(RuH(CO)(C₅H₄NCN)2(As(C₆H₅)3)2)B(C₆H₅)4 
• 566883-07-6 Ru(CO)(As(C₆H₅)3)(C₆H₄OCCH₃N)2(CH₂)4 
• 566883-01-0 Ru(CO)(As(C₆H₅)3)(C₆H₄OCHN)2(CH₂)4 
• 1006709-30-3 [Ru(OC₆H₃(CH₃)N₂C₆H₄)(CO)(As(C₆H₅)3)2] 
• 1006709-31-4 [Ru(OC₆H₃(CH₃)N₂C₆H₃Cl)(CO)(As(C₆H₅)3)2] 
• 1006709-32-5 [Ru(OC₆H₃(CH₃)N₂C₆H₃CH₃)(CO)(As(C₆H₅)3)2] 
• 1006709-34-7 [Ru(OC₆H₃(CH₃)N₂C₆H₃OC₂H₅)(CO)(As(C₆H₅)3)2] 
• 1006709-33-6 [Ru(OC₆H₃(CH₃)N₂C₆H₃OCH₃)(CO)(As(C₆H₅)3)2] 
• 1070876-55-9 [Ru(CO)(triphenylarsine)(OC₆H₄C(CHCHC₆H₄Cl)O)2] 
• 1030931-04-4 [Ru(CO)(triphenylarsine)2(2-[(2,4-dinitro-phenyl)-hydrazonomethyl]-6-methoxy-phenol(-2H))] 

Relevant academic research and scientific papers

Dehydrogenative Coupling of Ethanol and Ester Hydrogenation Catalyzed by Pincer-Type YNP Complexes

The "Y" donor group (Y = -OMe, -SEt, -PPh2, -NH2, -NMe2, -Py, pyrrolidinyl, quinolyl) of the pincer-type ruthenium complexes RuHCl(CO)[κ3-YNP] has a dramatic influence on the catalytic activity in the dehydrogenative homocoupling and cross-coupling of ethanol and ester hydrogenation reactions. The observations are connected with the mechanisms of the catalytic reactions, and this paper provides evidence for ester C-O bond formation/cleavage assisted by the bifunctional catalysts in an outer-sphere fashion, reminiscent of the Tishchenko chemistry.

HYDROGENATION AND DEHYDROGENATION CATALYST, AND METHODS OF MAKING AND USING THE SAME

The present application discloses complexes useful as catalysts for organic chemical synthesis including hydrogenation and dehydrogenation of unsaturated compounds or dehydrogenation of substrates. The range of hydrogenation substrate compounds includes esters, lactones, oils and fats, resulting in alcohols, diols, and triols as reaction products. The catalysts of current application can be used to catalyze a hydrogenation reaction under solvent free conditions. The present catalysts also allow the hydrogenation to proceed without added base, and it can be used in place of the conventional reduction methods employing hydrides of the main-group elements. Furthermore, the catalysts of the present application can catalyze a dehydrogenation reaction under homogenous and/or acceptorless conditions. As such, the catalysts provided herein can be useful in substantially reducing cost and improving the environmental profile of manufacturing processes for variety of chemicals.