75593-21-4

Upstream product

• 98713-50-9 2-methyl-4-phenyl-3-phenylthiobut-1-ene 
• 100-39-0 benzyl bromide 
• 702-00-1 (2-methylallyl)(phenyl)sulfane 

Downstream Products

• 37549-90-9 (Z)-(3-methylpent-2-en-1-yl)benzene 
• 62491-62-7 (E)-(3-methylpent-2-en-1-yl)benzene 
• 6700-98-7 2,3-dimethyl-4-phenyl-1-butene 
• 55177-36-1 (2E)-2-methyl-4-phenylbut-2-enal 
• 52497-56-0 (E)-2-methyl-4-phenyl-but-2-en-1-ol 

Relevant academic research and scientific papers

Regio- and Stero-selective Desulphurizative γ-Substitution of α-Substituted β-Methylallyl Sulphoxides and Sulphones with Lithium Dialkylcuprates providing Trisubstituted Olefins

α-Substituted β-methylallyl sulphoxides (2) and sulphones (3) undergo regio- and stereo-selective desulphurizative γ-substitution by the action of lithium dialkylcuprates in ether.The reaction provides a new method for the synthesis of trisubstituted E-ol

FACILE SYNTHESIS OF (E)-ALLYLIC ALCOHOLS BY ACID-CATALYZED MODIFICATION OF THE MISLOW-EVANS REARRANGEMENT OF ALLYLIC SULFOXIDES

The Mislow-Evans rearrangement of α,β- and α,γ-disubstituted allylic sulfoxides (2) to (E)-allylic alcohols (4) was found to occur under acidic conditions.By combination of this method with a catalytic oxidation of allylic sulfides (1), a novel one-pot tr