75619-34-0

Basic information

• Product Name: Benzyltris-(p-methoxyphenyl)phosphonium bromide
• Synonyms: Benzyltris-(p-methoxyphenyl)phosphonium bromide
• CAS NO: 75619-34-0
• Molecular Weight: 523.406
• Mol File: 75619-34-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzyltris-(p-methoxyphenyl)phosphonium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyltris-(p-methoxyphenyl)phosphonium bromide(75619-34-0)
• EPA Substance Registry System: Benzyltris-(p-methoxyphenyl)phosphonium bromide(75619-34-0)

Safety Data

• Hazardous Substances Data: 75619-34-0(Hazardous Substances Data)

Upstream product

• 855-38-9 P(p-CH₃OC₆H₄)3 
• 100-39-0 benzyl bromide 

Downstream Products

• 104-46-1 anethole 
• 14374-57-3 1-methoxy-4-(pent-1-en-1-yl)benzene 
• 107441-84-9 (E)-1-(hex-1-enyl)-4-methoxybenzene 
• 61866-52-2 1-butenyl-4-methoxybenzene 
• 54624-34-9 (4-methylpent-1-en-1-yl)benzene 
• 15325-61-8 3-methyl-1-phenyl-1-butene 
• 3412-44-0 1,3-diphenylpropene 
• 588-59-0 stilbene 
• 75619-30-6 Benzylidene-tris-(4-methoxy-phenyl)-λ⁵-phosphane 

Relevant articles and documents

Novel composite quaternary phosphonium salt and preparation method thereof and fluorescence application

The invention belongs to the technical field of functional material synthesis, and particularly relates to a novel composite quaternary phosphonium salt with fluorescence performance. The novel composite quaternary phosphonium salt is a compound composed

The Chemistry of Heteroarylphosphorus Compounds, Part 14 Effects of Heteroaryl Substituents at Phosphorus on the Steric Course of Wittig Reactions of Semistabilised and Stabilised Ylides

The cis-trans ratio of the stilbenes formed in Wittig reactions of semistabilised ylides (derived from benzyltri(hetero)arylphosphonium salts in ethanolic ethoxide) with benzaldehyde decreases markedly in the series 2-furyl > 2-thienyl > phenyl > 1-methylpyrrol-2-yl.The 2-furyl group favours a greater proportion of the cis-isomer than m-trifluoromethylphenyl, whereas the 1-methylpyrrol-2-yl group favours a greater proportion of the trans isomer than p-methoxyphenyl.Similarly, in Wittig reactions of carbonyl-stabilised ylides with benzaldehyde and acetaldehyde, the presence at phosphorus of 2-furyl groups results in a significant increase in the proportion of the cis-alkene compared to that formed from the related triphenylphosphonium ylide.These results are discussed in terms of both betaine and cycloaddition mechanisms for the Wittig reaction.Also discussed is their relevance to recent proposals concerning the eliminaton of alkene from the intermediate oxaphosphetan. - Keywords: Alkene cis-trans Ratio, Betaine Mechanism, Cycloaddition Mechanism