75854-97-6Relevant academic research and scientific papers
Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation
Naganawa, Yuki,Kawagishi, Mayu,Ito, Jun-Ichi,Nishiyama, Hisao
supporting information, p. 6873 - 6876 (2016/06/13)
The enantioselective desymmetrizing conjugate hydrosilylation of prochiral differently γ,γ-disubstituted cyclohexadienone derivatives 2 to furnish the corresponding cyclohexenones 4 with a remote chiral all-carbon quaternary center at the γ position is de
Diprotonation de derives phenoliques. Nouvelle synthese d'aryl-4 et d'aryl-3 cyclohexenones et de benzobicycloheptanes.
Jacquesy, Jean-Claude,Jouannetaud, Marie-Paule
, p. 295 - 303 (2007/10/02)
In SbF5-HF paracresol and its methyl ether are diprotonated and react with monosubstituted benzenes (chlorobenzene, toluene, acetanilide) to give as primary products and after hydrolysis 4-aryl cyclohexenones 4, 7, 9.The higher the acidity, the faster is
