76154-10-4

Basic information

• Product Name: (E)-N-(1-(4-bromophenyl)ethylidene)benzenamine
• Synonyms: (E)-N-(1-(4-bromophenyl)ethylidene)benzenamine
• CAS NO: 76154-10-4
• Molecular Weight: 274.16
• Mol File: 76154-10-4.mol
• Article Data: 36

Chemical Properties

• CAS DataBase Reference: (E)-N-(1-(4-bromophenyl)ethylidene)benzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N-(1-(4-bromophenyl)ethylidene)benzenamine(76154-10-4)
• EPA Substance Registry System: (E)-N-(1-(4-bromophenyl)ethylidene)benzenamine(76154-10-4)

Safety Data

• Hazardous Substances Data: 76154-10-4(Hazardous Substances Data)

Upstream product

• 766-96-1 4-bromo-1-ethynylbenzene 
• 62-53-3 aniline 
• 99-90-1 para-bromoacetophenone 
• 104-94-9 4-methoxy-aniline 
• 694-53-1 phenylsilane 
• 66751-80-2 1-(4-bromophenyl)diazoethane 
• 100-65-2 N-Phenylhydroxylamine 
• 536-74-3 phenylacetylene 
• 106-40-1 4-bromo-aniline 

Downstream Products

• 93807-01-3 N-phenyl-[1-(4-bromophenyl)ethyl]amine 
• 29325-58-4 N-(4-bromophenyl)-N-phenylacetamide 
• 95167-68-3 N-<α-(4-Brom-phenyl)-aethyl>-N-phenyl-N'.N'-dimethyl-aethylendiamin 
• 1621182-46-4 N-phenyl-N-[1-(4-bromophenyl)vinyl]-N-[dimethyl(phenyl)]silylamine 
• 1621182-47-5 N-phenyl-N-{2-[dimethyl(phenyl)]silyl-1-(4-bromophenyl)vinyl}-N-[dimethyl(phenyl)]silylamine 
• 5021-45-4 2-(4-bromophenyl)quinoxaline 
• 408327-64-0 2-(4-bromophenyl)quinolin-4(1H)-one 

Relevant articles and documents

Chiral imine-containing quinoline oxazoline compound and metal complex thereof as well as preparation method and application

The invention discloses a chiral imine-containing quinoline oxazoline compound which is high in optical purity and has a structural formula as shown in a formula (1), and discloses a preparation method of the chiral imine-containing quinoline oxazoline compound. The invention also discloses a metal complex obtained by complexing the chiral imine-containing quinoline oxazoline compound and a transition metal salt, wherein the metal complex is shown as a formula (6). The synthetic route is efficient, and the total yield of two steps can reach 85%. The metal complex of the chiral imine-containing quinoline oxazoline compound can be used as a catalyst to catalyze hydrosilylation or hydroboration on a carbon-carbon or carbon heteroatom double bond, and is especially suitable for preparing chiral organic compounds with high regioselectivity and optical selectivity.

Ruthenium N-Heterocyclic Carbene Complexes for Chemoselective Reduction of Imines and Reductive Amination of Aldehydes and Ketones

Chemoselective reduction of imines to secondary amines is catalyzed efficiently by tethered and untethered, half-sandwich ruthenium N-heterocyclic carbene (NHC) complexes at room temperature. The untethered Ru-NHC complexes are more efficient as catalysts for the reduction of aldimines and ketimines than the tethered complexes. Using the best untethered complex as a catalyst, electronic and steric demands on the reaction was probed using a series of imines. Chemoselectivity of the catalyst towards imine reduction was tested by performing inter and intramolecular competitive reactions in a variety of ways. The catalyst exhibits a very high TON and TOF under anaerobic conditions.

Rhodium-Catalyzed C=N Bond Formation through a Rebound Hydrolysis Mechanism and Application in β-Lactam Synthesis

A rhodium-catalyzed reaction of N-hydroxyanilines with diazo compounds to produce α-imino esters was developed. Distinct from the commonly accepted 1,2-H transfer for normal X-H insertion reactions, density functional theory calculations indicate that this transformation proceeds via a novel rebound hydrolysis mechanism. Furthermore, a three-component reaction was explored to synthesize highly functionalized β-lactams in good yields and diastereoselectivities.