7620-46-4Relevant articles and documents
Photochemical cyclization of N-butyl-N'-(9-acridinyl)thiourea.
de Leenheer,Sinsheimer,Burckhalter
, p. 273 - 274 (1972)
-
Reaction of Thiocarbonyl Fluoride Generated from Difluorocarbene with Amines
Yu, Jiao,Lin, Jin-Hong,Xiao, Ji-Chang
supporting information, p. 16669 - 16673 (2017/12/07)
The reaction of thiocarbonyl fluoride, generated from difluorocarbene, with various amines under mild conditions is described. Secondary amines, primary amines, and o-phenylenediamines are converted to thiocarbamoyl fluorides, isothiocyanates, and difluoromethylthiolated heterocycles, respectively. Thiocarbamoyl fluorides were further transformed into trifluoromethylated amines by using a one-pot process. Thiocarbonyl fluoride is generated in situ and is rapidly fully converted in one pot under mild conditions; therefore, no special safety precautions are needed.
Reaction of O-alkyl-N-substituted iminothiocarbonates with bromoacetyl bromide. A general method for the synthesis of 3-substituted 1,3-thiazolidine-2,4-diones
Imrich, Jan,Bernat, Juraj,Kristian, Pavol,Busov, Tatiana,Hocova, Slavka
, p. 432 - 436 (2007/10/03)
Reaction of sodium salts of O-methyl-N-substituted iminothiocaibonates with bromoacetyl bromide represents a new general method for preparation of 3-substituted 1,3-thiazolidine-2,4-diones in good yields and high purity. The structure of the synthesized products has been confirmed by 1H NMR, 13C NMR, IR and mass spectroscopy as well as by independent synthesis.