76200-34-5Relevant academic research and scientific papers
A General Procedure for Preparing α-Lithiosilanes. Generalization of the Peterson Olefination
Cohen, Theodore,Sherbine, James P.,Matz, James R.,Hutchins, Robert R.,McHenry, Barry M.,Willey, Paul R.
, p. 3245 - 3252 (2007/10/02)
A particularly convenient method for the preparation of α-lithiosilanes consists of the reductive lithiation of diphenyl thioacetals or thioketals with lithium 1-(dimethylamino)naphthalenide, treatment of the resulting anion with trimethylsilyl chloride,
Synthesis of Aldehydes from Phenylthiotrimethylsilylmethane
Ager, David J.
, p. 1131 - 1136 (2007/10/02)
Phenylthiotrimethylsilylmethyl-lithium (4) reacts with alkyl halides to give 1-phenylthio-1-trimethylsilylalkanes (5), which can also be prepared by the addition of alkyl-lithium to 1-phenylthio-1-trimethylsilylethene (8), or from bis(phenylthio)acetals (11).The 1-phenylthio-1-trimethylsilylalkanes (5) can be converted into the corresponding aldehyde (15) by oxidation to the sulphoxide (13), thermal rearrangement, and hydrolysis of the resultant O-silyl thioacetal (14).
ALDEHYDES FROM ALKYLLITHIUMS WITH 2-CARBON HOMOLOGATION
Ager, David J.
, p. 587 - 590 (2007/10/02)
1-Phenylthio-trimethylsilylalkanes, which are readily converted to aldehydes, are prepared by the addition of alkyllithiums to phenylthioethene, trimethylsilylethene and 1-phenylthio-1-trimethylsilylethene.
A NEW METHOD FOR CONVERTING ALKYL HALIDES TO HOMOLOGOUS ALDEHYDES
Ager, David J.,Cookson, Richard C.
, p. 1677 - 1680 (2007/10/02)
Phenylthiotrimethylsilylmethyl lithium can be alkylated and the product hydrolysed to the aldehydes by oxidation and rearrangement.
