76385-38-1

Basic information

• Product Name: phenyl[4-(prop-2-en-1-yl)phenyl]methanone
• CAS NO: 76385-38-1
• Molecular Formula: C₁₆H₁₄O
• Molecular Weight: 222.2818
• Mol File: 76385-38-1.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 347°C at 760 mmHg
• Flash Point: 149°C
• Density: 1.048g/cm³
• Vapor Pressure: 5.54E-05mmHg at 25°C
• Refractive Index: 1.574
• CAS DataBase Reference: phenyl[4-(prop-2-en-1-yl)phenyl]methanone(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl[4-(prop-2-en-1-yl)phenyl]methanone(76385-38-1)
• EPA Substance Registry System: phenyl[4-(prop-2-en-1-yl)phenyl]methanone(76385-38-1)

Safety Data

• Hazardous Substances Data: 76385-38-1(Hazardous Substances Data)

Upstream product

• 591-87-7 Allyl acetate 
• 90-90-4 (4-bromophenyl)(phenyl)methanone 
• 106-95-6 allyl bromide 
• 53317-08-1 9-allyl-9-bora-bicyclo[3.3.1]nonane 
• 124643-34-1 p-benzoylphenyl triflate 
• 6136-66-9 4-iodobenzophenone 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 24850-33-7 allyltributylstanane 

Downstream Products

• 1334204-40-8 C₂₄H₂₉BO 
• 41882-77-3 4-(3-hydroxycarbonylpropyl)-benzophenone 

Relevant articles and documents

Cobalt-Catalyzed Allylic C(sp3)-H Carboxylation with CO2

Catalytic carboxylation of the allylic C(sp3)-H bond of terminal alkenes with CO2 was developed with the aid of a Co/Xantphos complex. A wide range of allylarenes and 1,4-dienes were successfully transformed into the linear styrylacetic acid and hexa-3,5-dienoic acid derivatives in moderate to high yields, with excellent regioselectivity. The carboxylation showed remarkable functional group tolerability, so that selective addition to CO2 occurred in the presence of other carbonyl groups such as amide, ester, and ketone. Since styrylacetic acid derivatives can be readily converted into optically active γ-butyrolactones through Sharpless asymmetric dihydroxylation, this allylic C(sp3)-H carboxylation showcases a facile synthesis of γ-butyrolactones from simple allylarenes via short steps.

Suzuki reactions with B-allyl-9-borabicyclo[3.3.1]nonane (B-allyl-9-BBN)

The mixture of borate complexes formed on treatment of B-allyl-9-BBN with KOMe readily undergoes Suzuki reactions in the presence of catalytic amounts of Pd(0) complexes, thus transferring their allyl moiety to aryl bromides, -iodides or -triflates.

RADIKALISCHE REAKTIONSWEGE BEI THERMISCH INDUZIERTEN UMSETZUNGEN VON ZIRCONOCENKOMPLEXEN

The formation of products 2, 3 and 4(a-l) from both the reaction of εta2-bezophenone zirconocene 1 with alkyl halides and the thermolysis of the α-(Cp2ZrCl)-substituted benzhydrylmethylether 9, the latter proceeding with anchimeric assistance of the metal, can be understood assuming a stepwise reaction path through radical intermediates.The proposed intermediate transition-metal benzophenone ketyl 12 exhibits a reaction pattern differing from analogous main-group-metal ketyls.