76710-52-6Relevant academic research and scientific papers
Intramolecular base-stabilised adducts of main group halides
Aldridge, Simon,Calder, Richard J.,Coombs, Deborah L.,Jones, Cameron,Steed, Jonathan W.,Coles, Simon,Hursthouse, Michael B.
, p. 677 - 686 (2007/10/03)
The coordination chemistry of alkoxo and amido ligands bearing pendant nitrogen or sulfur donors has been developed to include examples of main group complexes. The structural implications of amido ligand coordination augmented by a tethered pyridyl base have been investigated for group 13 and 14 derivatives {[6-(Me3SiN)-2-Me-C5H3N]SnCl3 and [6-(Me3SiN)-2-Me-C5H3N]BBr2}. Furthermore, the scope, kinetics and mechanism of the synthesis of alkoxo and amido derivatives from trimethylsilyl substituted precursors have been investigated in depth. The methodology is found to be applicable to a range of ligand frameworks of varying flexibility, stabilised by one or two "tether" arms.
Fluorophosphoranes as Lewis acids. The conditions of access to hexacoordinated neutral adducts via the intramolecular addition of an electrondonor
Robert, Dominique,Gawad, Hoda Abdel,Riess, Jean G.
, p. 511 - 516 (2007/10/02)
The possibility of obtaining bicyclic neutral hexacoordinated fluorophosphorus adduct of type 2 was investigated for R=F, Me, Ph and X=O, S, NH, NMe, NtBu NPh.Adduct 2g was formed predominantly only in the case where R=F and X=S.In all the othe
