76859-76-2

Basic information

• Product Name: (E)-1-bromo-4-((4-methoxystyryl)sulfonyl)benzene
• Synonyms: (E)-1-bromo-4-((4-methoxystyryl)sulfonyl)benzene
• CAS NO: 76859-76-2
• Molecular Weight: 353.236
• Mol File: 76859-76-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-1-bromo-4-((4-methoxystyryl)sulfonyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-bromo-4-((4-methoxystyryl)sulfonyl)benzene(76859-76-2)
• EPA Substance Registry System: (E)-1-bromo-4-((4-methoxystyryl)sulfonyl)benzene(76859-76-2)

Safety Data

• Hazardous Substances Data: 76859-76-2(Hazardous Substances Data)

Upstream product

• 637-69-4 4-Methoxystyrene 
• 98-58-8 4-bromobenzenesulfonyl chloride 
• 2297-64-5 p-bromophenylsulfonyl hydrazide 
• 943-89-5 (E)-3-(4-methoxyphenyl)acrylic acid 
• 34176-08-4 sodium 4-bromobenzenesulfinate 
• 27691-36-7 Diethyl(4-bromphenylmercapto)-methanphosphonat 
• 27691-35-6 1-bromo-4-[(chloromethyl)sulfanyl]benzene 
• 27691-37-8 Diethyl(4-bromphenylsulfono)-methanphosphonat 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 73628-17-8 C₁₆H₁₅BrO₃S 

Relevant articles and documents

Synthesis of vinyl sulfones through sulfonylation of styrenes with sulfonyl chlorides under metal-free conditions

A hypervalent iodine reagent-mediated sulfonylation of styrenes with sulfonyl chlorides was developed for the synthesis of vinyl sulfones. The reaction proceeded under metal-free, mild and neutral conditions without extra oxidants or bases. It also exhibited good air and moisture tolerance, broad substrate scope and high chemo-selectivity, affording the vinyl sulfones in moderate to good yields.

Copper-catalyzed decarboxylative sulfonylation of α,β-unsaturated carboxylic acids

Copper-catalyzed, ligand-promoted decarboxylative coupling of readily available α,β-unsaturated acids with sodium aryl sulfinates is presented. This method provides a new avenue for the synthesis of vinyl sulfones via a decarboxylative radical coupling st