7708-28-3

Basic information

• Product Name: Methanol, (phenylmethoxy)-, acetate
• Synonyms: Essigsaeure-benzyloxymethylester;benzyloxymethyl acetate;acetoxymethyl benzylether;Benzyloxy-acetoxy-methan;acetic acid benzyloxymethyl ester
• CAS NO: 7708-28-3
• Molecular Formula: C10H12O3
• Molecular Weight: 180.203
• Mol File: 7708-28-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Methanol, (phenylmethoxy)-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Methanol, (phenylmethoxy)-, acetate(7708-28-3)
• EPA Substance Registry System: Methanol, (phenylmethoxy)-, acetate(7708-28-3)

Safety Data

• Hazardous Substances Data: 7708-28-3(Hazardous Substances Data)

Upstream product

• 100-51-6 benzyl alcohol 
• 5658-46-8 ((2-methylallyloxy)methyl)benzene 
• 3587-60-8 Benzyloxymethyl chloride 
• 64-19-7 acetic acid 
• 108-24-7 acetic anhydride 
• 88738-41-4 <<(methoxyethoxy)methoxy>methyl>benzene 
• 625-56-9 Chloromethyl acetate 
• 127-08-2 potassium acetate 
• 109-87-5 Dimethoxymethane 

Downstream Products

• 6278-91-7 4-(benzyloxy)-2-butanone 
• 1154032-29-7 1-(benzyloxymethyl)-5-chloro-6-(2,4-dichlorophenoxymethyl)uracil 
• 1154032-28-6 1-(benzyloxymethyl)-6-(2,4-dichlorophenoxymethyl)-5-iodouracil 
• 1154032-30-0 1-(benzyloxymethyl)-5-bromo-6-(2,4-dichlorophenoxymethyl)uracil 
• 190835-51-9 1-Benzyl-3-benzyloxymethyl-2,2-dioxo-2,3-dihydro-1H-2λ⁶-benzo[1,2,6]thiadiazin-4-one 
• 221632-89-9 3-Benzyloxymethyl-2,2-dioxo-2,3-dihydro-1H-2λ⁶-benzo[1,2,6]thiadiazin-4-one 
• 190835-45-1 3-Benzyl-1-benzyloxymethyl-2,2-dioxo-2,3-dihydro-1H-2λ⁶-benzo[1,2,6]thiadiazin-4-one 

Relevant articles and documents

Acid catalyzed rearrangement of vinyl and ketene acetals

Substituted vinyl and ketene acetals undergo smooth oxygen-to-carbon rearrangement with a catalytic amount of TMSOTf to afford chain-extended ketones or esters, respectively. The developed procedure has been applied to the stereoselective synthesis of C-glycosides from the corresponding anomeric vinyl ethers.

Cleavage of 2-methoxyethoxymethyl ethers catalyzed by cerium(IV) ammonium nitrate (CAN) in acetic anhydride

The reactions of 2-methoxyethoxymethyl (MEM) ethers 1 with a catalytic amount of cerium(IV) ammonium nitrate (CAN) in acetic anhydride gave the corresponding mixed acetal esters 2 and acetates 3.

Synthesis of acyclic thieno[3,2-d]pyrimidine nucleosides and azido derivatives as potential anti-HIV agents

A series of thieno[3,2-d]pyrimidine-2,4-diones alkylated with acyclic chains have been synthesized related to the antiherpetic agents (acyclovir and ganciclovir) and to EBPU which was reported to display in vitro antiviral activity against human immunodeficiency virus type 1 (HIV-1). Conversion of the hydroxy-acyclic nucleosides into their azido derivatives was then examined using triphenylphosphine - carbon tetraiodide - sodium azide. All the compounds, however, did not exhibit any significant inhibitory activity against HIV-1 in CEM cl 13 cells.