772-53-2

Basic information

• Product Name: PHENYL TRIFLUOROVINYL ETHER
• Synonyms: PHENYL TRIFLUOROVINYL ETHER;[(Trifluorovinyl)oxy]benzene
• CAS NO: 772-53-2
• Molecular Formula: C₈H₅F₃O
• Molecular Weight: 174.12
• Mol File: 772-53-2.mol

Chemical Properties

• Boiling Point: 125.7°C at 760 mmHg
• Flash Point: 35.5°C
• Appearance: /
• Density: 1.248g/cm³
• Vapor Pressure: 14.6mmHg at 25°C
• Refractive Index: 1.454
• CAS DataBase Reference: PHENYL TRIFLUOROVINYL ETHER(CAS DataBase Reference)
• NIST Chemistry Reference: PHENYL TRIFLUOROVINYL ETHER(772-53-2)
• EPA Substance Registry System: PHENYL TRIFLUOROVINYL ETHER(772-53-2)

Safety Data

• Hazardous Substances Data: 772-53-2(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
Phenyl trifluorovinyl ether is used as a reagent in organic synthesis for its ability to facilitate various chemical reactions, contributing to the formation of complex organic molecules.
Used in Industrial Processes:
In industrial processes, Phenyl trifluorovinyl ether is utilized as a solvent due to its unique properties that make it suitable for dissolving certain substances and aiding in the efficiency of the process.
Used in Specialty Polymers:
Phenyl trifluorovinyl ether is incorporated as a component in the production of specialty polymers, where its heat resistance and stability are particularly advantageous for creating polymers with specific characteristics required for high-performance applications.
Used in High-Temperature Applications:
Due to its heat resistance, Phenyl trifluorovinyl ether is employed in applications that require materials to withstand high temperatures, ensuring the compound's performance and integrity under such conditions.

InChI:InChI=1/C8H5F3O/c9-7(10)8(11)12-6-4-2-1-3-5-6/h1-5H

Upstream product

• 354-04-1 1,2-dibromo-1,1,2-trifluoroethane 
• 108-95-2 phenol 
• 116-14-3 polytetrafluoroethylene 
• 139-02-6 sodium phenoxide 
• 350-57-2 1,1,2,2-tetrafluoroethyl phenyl ether 
• 206667-03-0 C₉H₅F₄O₃^(1-)*K⁽¹⁺⁾ 
• 100-67-4 potassium phenolate 
• 1252017-26-7 2-phenoxytetrafluoropropionic acid 
• 83015-28-5 1,1,2,2-tetrafluoro-1-bromo-2-phenoxyethane 

Downstream Products

• 1594970-70-3 C₈H₅ClF₈OS 
• 864715-99-1 2-bromo-1-(4-((trifluorovinyl)oxy)phenyl)propan-1-one 
• 1427-46-9 C₁₆H₁₀F₆O₂ 

Relevant articles and documents

METHOD OF MAKING PERFLUOROCYCLOBUTANE-CONTAINING MONOMER

The invention pertains to a multi-step process for making polyfunctional aromatic compounds comprising two phenyl rings bearing reactive groups susceptible of polycondensation reaction to provide polycondensed polymers, said method using economic raw materials, and possessing high selectivity and overall yield.

Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroethylene

The copper(I)-mediated generation of -OCF2CF2- moieties by the oxycupration of tetrafluoroethylene (TFE) using either copper aryloxides or alkoxides is disclosed. The key intermediates, 2-aryloxy-1,1,2,2-tetrafluoroethyl and 2-alkoxy

Method for preparing trifluorovinyl aryl ether compound from dihalide trifluoroethane

The invention relates to a method for synthesizing a trifluorovinyl aryl ether compound, and belongs to the field of chemical synthesis. The dihalide trifluoroethane is taken as the starting material, reacts with a phenolic compound under proper conditions to synthesize the trifluorovinyl aryl ether compound. Compared with the traditional method, the provided synthesis method has the characteristics of mild reaction condition, simple operation, moderate yield and the like, has the advantages of simple process, low cost, low pollution and the like, and is expected to realize industrialized production.

Nucleophilic difluoroalkylation of benzophenones, benzaldehydes and Schiff's bases by tetrafluoroethyl ether and difluoroacetamide

From gem-difluoromethyl group of 1,1,2,2-tetrafluoroethyl ether and 2,2-difluoroalkylamide, proton can be removed by potassium bis(trimethylsilyl)amide in DMF, THF or toluene. The generated nucleophiles are then condensed with benzophenones, benzaldehydes or Schiff's bases to provide new fluorinated alcohols and amines. Some interesting solvent effects are also observed.

Pentafluorosulfanyldifluoroacetic acid: Rebirth of a promising building block

Three novel, easily scalable routes for the synthesis of pentafluorosulfanyldifluoroacetic acid, SF5CF2C(O)OH, are described. Reactions of its acid chloride with amines and alcohols led to a small library of 15 amides and five esters

A novel semi-fluorinated graft copolymer containing perfluorocyclobutyl aryl ether-based backbone

The synthesis of a series of novel semi-fluorinated graft copolymers bearing perfluorocyclobutyl (PFCB) aryl ether-based backbone and polystyrene side chains is described. This work initially focused on the synthesis of a trifluorovinyl ether (TFVE) monomer containing a bromine atom, which could be employed as an initiating site for atom transfer radical polymerization (ATRP). Thermal cyclopolymerization of this TFVE monomer provided a macromolecular initiator followed by subsequent initiating ATRP of styrene to afford the desired PFCB aryl ether-based graft copolymers.

Influence of structural factors on the thermolysis of 2- alkoxytetrafluoropropionic acid salts

2,2,2-Trifluoroethyl and phenyl trifluorovinyl ethers were obtained by the thermolysis of 2-substituted potassium tetrafluoropropionates ROCF(CF 3)COOK (R = CF3CH2; Ph). The reaction mechanism is analyzed.

Synthesis and characterization of a novel perfluorocyclobutyl aromatic ether-based ABA triblock copolymer

A novel perfluorocyclobutyl aromatic ether-based ABA triblock copolymer (A: polystyrene block; B: perfluorocyclobutyl aromatic ether-based fluoropolymer block) was synthesized by combination of atom transfer radical polymerization (ATRP) of styrene and th

Preparation of halofluoroalkyl ethers

Alkyl or aryl 1,1-difluoroalkyl ethers, e.g., 1,1,2-trifluoro-2-chloro-2-iodoethyl phenyl ether, are prepared by reacting an alkoxide or phenoxide with a 1,1-difluoro-1,2-dihaloethane (with the proviso that halo is not fluoro and at least one of the halo substituents is bromo or iodo) in an organic solvent at temperatures ranging from about -30° C. to about 100° C. These compounds may be dehalogenated with zinc to form the corresponding vinyl ethers. The reaction of halogen derivatives of fluorocarbons with nucleophiles is dramatically facilitated by a bromo or iodo substituent in the beta position.