77210-23-2

Upstream product

• 98-88-4 benzoyl chloride 
• 6752-48-3 methyl 4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 33535-04-5 methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 19877-02-2 methyl 4,6-O-benzylidene-2-deoxy-α-D-lyxo-hexopyranoside 
• 61-58-5 2-deoxy-D-lyxo-hexopyranose 
• 100-52-7 benzaldehyde 

Downstream Products

• 77180-74-6 methyl 3,4-di-O-benzoyl-2,6-dideoxy-α-D-lyxo-hexopyranoside 
• 13322-79-7 methyl 2,6-dideoxy-α-D-lyxo-hexopyranoside 
• 77180-73-5 methyl 3,4-di-O-benzoyl-6-bromo-2,6-dideoxy-α-D-lyxo-hexopyranoside 

Relevant academic research and scientific papers

An approach to the site-selective deoxygenation of hydroxy groups based on catalytic phosphoramidite transfer

Selective: The deoxygenation of simple and complex natural products employing a readily synthesized phosphoramidite and tetrazole catalysts can be executed as a two-step process, without the need to isolate intermediate deoxygenation precursors. Furthermore, a peptide-based tetrazole catalyst controls the site selectivity of deoxyerythromycin synthesis (see scheme), thus overcoming the notorious challenges with unprotected erythromycin A. Copyright

SYNTHESIS OF METHYL 2,6-DIDEOXY-α-D-XYLO- AND α-D-LYXO-HEXOPYRANOSIDE

Synthesis of the title glycosides from methyl 3,4-anhydro-6-deoxy-α-D-galactopyranoside and 2-deoxy-D-lyxo-hexopyranose is described.