77455-33-5

Upstream product

• 111549-75-8 benzyl 3-O-allyl-2,4-di-O-benzyl-6-O-trityl-α-D-mannopyranoside 
• 100-39-0 benzyl bromide 
• 77455-30-2 benzyl 6-O-triphenylmethyl-α-D-mannopyranoside 
• 15548-45-5 (2S,3S,4S,5S,6R)-2-benzyloxy-6-(hydroxymethyl)tetrahydropyran-3,4,5-triol 
• 50-99-7 D-mannitol 
• 100-51-6 benzyl alcohol 
• 53929-39-8 benzyl 3-O-allyl-2-O-benzyl-4,6-benzylidene-α-D-mannopyranoside 
• 58650-53-6 benzyl endo-2,3:4,6-di-O-benzylidene-α-D-mannopyranoside 
• 14897-54-2 benzyl 2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 

Downstream Products

• 111549-79-2 benzyl 2,4,6,7-tetra-O-benzyl-L-glycero-α-D-mannoheptopyranoside 
• 111549-78-1 (2S,3S,4S,5S,6R)-4-Allyloxy-2,3,5-tris-benzyloxy-6-((S)-1,2-bis-benzyloxy-ethyl)-tetrahydro-pyran 
• 111556-46-8 C₈₀H₈₄O₁₃ 
• 111549-77-0 (R)-1-((2R,3S,4S,5S,6S)-4-Allyloxy-3,5,6-tris-benzyloxy-tetrahydro-pyran-2-yl)-2-benzyloxy-ethanol 
• 111549-77-0 (S)-1-((2R,3S,4S,5S,6S)-4-Allyloxy-3,5,6-tris-benzyloxy-tetrahydro-pyran-2-yl)-2-benzyloxy-ethanol 
• 86342-18-9 benzyl 2,4-di-O-benzyl-α-D-rhamnopyranoside 
• 86342-16-7 benzyl 3-O-allyl-2,4-di-O-benzyl-α-D-rhamnopyranoside 
• 86342-14-5 benzyl 3-O-allyl-2,4-di-O-benzyl-6-O-(p-toluenesulfonyl)-α-D-mannopyranoside 
• 69401-46-3 benzyl 2,4-di-O-benzyl-α-D-mannopyranoside 
• 77455-35-7 benzyl 3-O-<2-acetamido-3,6-di-O-acetyl-2-deoxy-4-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-β-D-glucopyranosyl>-6-O-allyl-2,4-di-O-benzyl-α-D-mannopyranoside 
• 77469-42-2 benzyl 3-O-<2-acetamido-3,6-di-O-acetyl-2-deoxy-4-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-β-D-glucopyranosyl>-2,4-di-O-benzyl-α-D-mannopyranoside 
• 77455-34-6 benzyl 6-O-allyl-2,4-di-O-benzyl-α-D-mannopyranoside 
• 58527-93-8 benzyl 2,4-di-O-benzyl-3-O-(prop-1-enyl)-α-D-mannopyranoside 
• 111549-76-9 (2S,3S,4S,5S,6S)-4-Allyloxy-3,5,6-tris-benzyloxy-tetrahydro-pyran-2-carbaldehyde 

Relevant academic research and scientific papers

THE SYNTHESIS OF THE HEPTOSE REGION OF THE GRAM-NEGATIVE BACTERIAL CORE OLIGOSACCHARIDES

Disaccharides linked α(1-3) and α(1-7) and a trisaccharide linked α(1-7) and α(1-3) have been synthesized from suitably blocked L-glycero-D-mannoheptose derivatives using the trichloroacetimidate approach.

CHEMO-, STEREO- AND REGIOSELECTIVE HYDROGENOLYSIS OF CARBOHYDRATE BENZYLIDENE ACETALS. SYNTHESIS OF BENZYL ETHERS OF BENZYL α-D-, METHYL β-D-MANNOPYRANOSIDES AND BENZYL α-D-RHAMNOPYRANOSIDE BY RING CLEAVAGE OF BENZYLIDENE DERIVATIVES WITH THE LiAlH4-AlCl3

Treatment of benzyl α-(1) and methyl β-D-mannopyranoside (2) with α,α-dimethoxytoluene gave the exo and endo isomers (3,5 and 4,6) of the dibenzylidene derivatives of 1 and 2.Hydrogenolysis of the exo isomers (3 and 5) with a molar equivalent of AlH2Cl ga

Synthesis of O-β-D-Galactopyranosyl-(1->4)-O-2-acetamido-2-deoxy-β-D-glucopyranosyl-(1->3)-D-mannose, a Postulated Trisaccharide of Human Erythrocyte Membrane Sialoglycoprotein

Monoallylation of tributylstannylated benzyl 6-O-trityl-α-D-mannopyranoside (3) was efficiently catalysed by tetrabutylammonium bromide to give the 3-O- (4) and 2-O- (5) allyl ethers in 62 and 15percent yields, respectively.Compound (4) was converted into