774591-92-3

Upstream product

• 869107-20-0 Trifluoro-methanesulfonic acid (2R,3S,4R,5R,6S)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-(4-methoxy-phenoxy)-tetrahydro-pyran-3-yl ester 
• 68-12-2 N,N-dimethyl-formamide 
• 869107-36-8 4-methoxyphenyl 2,3,6-tri-O-benzyl-β-D-galactopyranoside 
• 3150-20-7 4-methoxyphenyl β-D-glucopyranoside 
• 2872-65-3 p-methoxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 
• 150-76-5 4-methoxy-phenol 
• 604-69-3 β-D-glucose pentaacetate 
• 1352550-64-1 4-methoxyphenyl 2,3,6-tri-O-benzyl-4-O-chloroacetyl-β-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 765952-64-5 4-methoxyphenyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-glucopyranoside 

Downstream Products

• 1186009-42-6 C₄₈H₅₄O₁₆ 
• 1381871-20-0 2,6-anhydro-3,4,7-tri-O-benzyl-5-O-((2-naphthyl)methyl)-1-deoxy-1-ethoxysulfonyl-D-gluco-hept-1-enitol 
• 1381871-19-7 p-methoxyphenyl 3,4,7-tri-O-benzyl-5-O-((2-naphthyl)methyl)-1-deoxy-1-ethoxysulfonyl-α-D-gluco-hept-2-ulopyranosyl-(2->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 223582-41-0 C₃₇H₄₀O₈S 
• 1319716-08-9 4-methoxyphenyl 2,3,6-tri-O-benzyl-4-O-(3,4,5,7-tetra-O-benzyl-1-deoxy-1-ethoxysulfonyl-α-D-glucohept-2-ulopyranosyl)-β-D-glucopyranoside 
• 1319716-01-2 2,6-anhydro-3,4,5,7-tetra-O-benzyl-1-ethoxysulfonyl-D-glucohept-2-enitol 
• 1205570-55-3 para-methoxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl-(1->4)-2,3,6-tri-O-acetyl-β-D-glucopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 1172114-32-7 4-methoxyphenyl (2,3-di-O-acetyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 774591-89-8 4-methoxyphenyl (6-O-benzyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 774591-90-1 4-methoxyphenyl 2,3,6-tri-O-benzyl-4-O-(6-O-benzyl-4-deoxy-4-azido-β-D-galactopyranosyl)-β-D-glucopyranoside 
• 774591-93-4 4-methoxyphenyl (3,4-di-O-acetyl-6-O-benzyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 774591-94-5 4-methoxyphenyl (3,4-di-O-acetyl-4-azido-6-O-benzyl-4-deoxy-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

Stereoinversion of Stereocongested Carbocyclic Alcohols via Triflylation and Subsequent Treatment with Aqueous N,N-Dimethylformamide

A convenient method for the stereoinversion of secondary alcohols, applicable to stereocongested carbocyclic substrates, is reported. A simple three-step procedure, including triflylation of the hydroxy group, nucleophilic oxygenative displacement by the treatment with aqueous N,N-dimethylformamide (DMF), and methanolysis, allowed for efficient stereoinversion of various substrates, including sugar derivatives, in one pot.

HUMAN iNKT CELL ACTIVATION USING GLYCOLIPIDS

Glycosphingolipids (GSLs) compositions and methods for iNKT-independent induction of chemokines are disclosed.

Efficient and selective removal of chloroacetyl group promoted with tetra-n-butylammonium fluoride (TBAF)

A practical method for the efficient and selective cleavage of chloroacetyl protecting group using tetra-n-butylammonium fluoride (TBAF) in THF solution at rt was disclosed.

Interhalogens (ICl/IBr) and AgOTf in thioglycoside activation; synthesis of bislactam analogues of ganglioside GD3

The novel promoter system IX/AgOTf (X = Cl or Br) has been evaluated in the synthesis of two bislactam analogues of GD3. We have carried out two high-yielding galactosylations in 97% and 98% yield, respectively, using ICl/AgOTf, and four sialylations in 9