869107-36-8

Basic information

• Product Name: 4-Methoxyphenyl 2,3,6-Tri-O-benzyl-beta-D-galactopyranoside
• Synonyms: 4-Methoxyphenyl 2,3,6-Tri-O-benzyl-beta-D-galactopyranoside;4-Methoxyphenyl 2,3,6-Tri-O-benzyl-β-D-galactopyranoside
• CAS NO: 869107-36-8
• Molecular Formula: C₃₄H₃₆O₇
• Molecular Weight: 556.64544
• Mol File: 869107-36-8.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 700.022°C at 760 mmHg
• Flash Point: 377.16°C
• Appearance: /
• Density: 1.243g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.618
• CAS DataBase Reference: 4-Methoxyphenyl 2,3,6-Tri-O-benzyl-beta-D-galactopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Methoxyphenyl 2,3,6-Tri-O-benzyl-beta-D-galactopyranoside(869107-36-8)
• EPA Substance Registry System: 4-Methoxyphenyl 2,3,6-Tri-O-benzyl-beta-D-galactopyranoside(869107-36-8)

Safety Data

• Hazardous Substances Data: 869107-36-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C34H36O7/c1-36-28-17-19-29(20-18-28)40-34-33(39-23-27-15-9-4-10-16-27)32(38-22-26-13-7-3-8-14-26)31(35)30(41-34)24-37-21-25-11-5-2-6-12-25/h2-20,30-35H,21-24H2,1H3/t30-,31-,32-,33-,34+/m0/s1

Upstream product

• 100-39-0 benzyl bromide 
• 159922-50-6 4-methoxyphenyl 2,6-di-O-benzyl-β-D-galactopyranoside 
• 176299-96-0 4-methoxyphenyl 4,6-O-benzylidene-β-D-galactopyranoside 
• 3150-20-7 4-methoxyphenyl β-D-glucopyranoside 
• 2872-65-3 p-methoxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 
• 150-76-5 4-methoxy-phenol 
• 604-69-3 β-D-glucose pentaacetate 

Downstream Products

• 1585232-88-7 4-methoxyphenyl 3,4,6-tri-O-acetyl-2-amino-2-deoxy-β-D-galactopyranosyl-(1→4)-2,3,6-tri-O-benzyl-β-D-galactopyranoside 
• 1585232-90-1 4-methoxyphenyl 2-acetamido-4,6-di-O-acetyl-2-deoxy-β-D-galactopyranosyl-(1→4)-2,3,6-tri-O-benzyl-β-D-galactopyranoside 
• 774591-92-3 4-methoxyphenyl 2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 1417417-74-3 p-methoxyphenyl (2,3,4-tri-O-benzoyl-α-6-O-tert-butyldiphenylsilyl-β-D-glucopyranosyl)-(1→4)-2,3,6-tri-O-benzyl-β-D-galactopyranoside 
• 1393114-53-8 p-methoxyphenyl (2-O-benzyl-4,6-O-benzylidene-α-D-galactopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-N-phthalimido-β-D-glucopyranoside 
• 1393114-58-3 (2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->3)-(4,6-di-O-acetyl-2-azido-2-deoxy-α-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α/β-D-galactopyranosyl trichloroacetimidate 
• 1393114-57-2 p-methoxyphenyl (2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->3)-(4,6-di-O-acetyl-2-azido-2-deoxy-α-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranoside 
• 1393114-55-0 p-methoxyphenyl (2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->3)-(4,6-O-benzylidene-2-azido-2-deoxy-α-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranoside 
• 1393114-54-9 p-methoxyphenyl (4,6-O-benzylidene-2-azido-2-deoxy-α-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranoside 

Relevant articles and documents

Stereoselective Synthesis of α-3-Deoxy- D -manno-oct-2-ulosonic Acid (α-Kdo) Glycosides Using 5,7-O-Di-tert-butylsilylene-Protected Kdo Ethyl Thioglycoside Donors

An efficient methodology for the synthesis of α-Kdo glycosidic bonds has been developed with 5,7-O-di-tert-butylsilylene (DTBS) protected Kdo ethyl thioglycosides as glycosyl donors. The approach permits a wide scope of acceptors to be used, thus affording biologically significant Kdo glycosides in good to excellent chemical yields with complete α-selectivity. The synthetic utility of an orthogonally protected Kdo donor has been demonstrated by concise preparation of two α-Kdo-containing oligosaccharides.

A facile method for β-selenoglycoside synthesis using β-p-methylbenzoyl selenoglycoside as the selenating unit

(Chemical Equation Presented) The reaction between α-glycosyl bromides and potassium p-methylselenobenzoate yields β-p-methylbenzoyl selenoglycosides. The acyl selenoglycosides were activated by the action of a secondary amine and Cs2CO3 to produce an anomeric selenolate anion, which reacted in situ with various electrophiles to yield novel selenoglycosides while retaining the anomeric stereochemistry.