77585-87-6

Basic information

• Product Name: N'-(4-bromophenyl)-N-methyl-N-phenylurea
• Synonyms: N'-(4-bromophenyl)-N-methyl-N-phenylurea
• CAS NO: 77585-87-6
• Molecular Formula: C₁₄H₁₃BrN₂O
• Molecular Weight: 305.16982
• Mol File: 77585-87-6.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 453°Cat760mmHg
• Flash Point: 227.8°C
• Appearance: /
• Density: 1.491g/cm³
• Vapor Pressure: 2.14E-08mmHg at 25°C
• Refractive Index: 1.681
• CAS DataBase Reference: N'-(4-bromophenyl)-N-methyl-N-phenylurea(CAS DataBase Reference)
• NIST Chemistry Reference: N'-(4-bromophenyl)-N-methyl-N-phenylurea(77585-87-6)
• EPA Substance Registry System: N'-(4-bromophenyl)-N-methyl-N-phenylurea(77585-87-6)

Safety Data

• Hazardous Substances Data: 77585-87-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H13BrN2O/c1-17(13-5-3-2-4-6-13)14(18)16-12-9-7-11(15)8-10-12/h2-10H,1H3,(H,16,18)

Upstream product

• 100-61-8 N-methylaniline 
• 124-38-9 carbon dioxide 
• 106-40-1 4-bromo-aniline 
• 14917-59-0 p-bromobenzoyl azide 

Downstream Products

• 1043906-11-1 1-(4-bromophenyl)-3-methyl-1,3-dihydro-2H-benzo[d]imidazol-2-one 

Relevant articles and documents

2,2,2-Trifluroenthanol promoted synthesis of unsymmetrical ureas from dioxazolones and amines via tandem lossen rearrangement/condensation process

A 2,2,2-trifluroenthanol (TFE) promoted synthesis of unsymmetric ureas was described. This approach enabled the construction of a variety of ureas from the readily prepared and easy-to-handle dioxazolones and amines via tandem Lossen rearrangement/condensation process. The reaction featured mild conditions for the urea synthesis under metal-free conditions, which was successively applied in the scale-up synthesis of herbicides Monuro and Isoproturon.