87014-19-5

Upstream product

• 87014-18-4 (3aR,6S,7aR)-3a-(3,4-Dimethoxy-phenyl)-6-hydroxy-hexahydro-benzofuran-2-one 
• 440361-91-1 [1-(3,4-dimethoxy-phenyl)-4-oxo-cyclohex-2-enyl]-acetaldehyde 
• 77783-92-7 (+/-)-2-(3,4-dimethoxyphenyl)penten-4-al 
• 188476-12-2 4-((E)-2-Allyloxy-vinyl)-1,2-dimethoxy-benzene 
• 440361-90-0 4-allyl-4-(3,4-dimethoxyphenyl)cyclohex-2-enone 
• 87014-17-3 Acetic acid (1R,3S,6S)-6-(3,4-dimethoxy-phenyl)-8-oxo-bicyclo[4.2.0]oct-3-yl ester 
• 57707-02-5 4,4-(ethylenedioxy)-1-vinylcyclohexene 
• 4746-97-8 cyclohexanedione monoethylene ketal 
• 170011-47-9 1,4-dioxaspiro[4.5]dec-7-en-8-yl trifluoromethanesulfonate 
• 121537-78-8 [(7R,8S)-7-Acetoxy-8-(3,4-dimethoxy-phenyl)-1,4-dioxa-spiro[4.5]dec-8-yl]-acetic acid methyl ester 
• 121537-76-6 2-carboxymethyl-5,5-ethylenedioxy-2-(3',4'-dimethoxyphenyl)cyclohexyl acetate 
• 70779-53-2 Acetic acid (7R,8S)-8-allyl-8-(3,4-dimethoxy-phenyl)-1,4-dioxa-spiro[4.5]dec-7-yl ester 
• 70779-54-3 Acetic acid (7R,8S)-8-(3,4-dimethoxy-phenyl)-8-(2-oxo-ethyl)-1,4-dioxa-spiro[4.5]dec-7-yl ester 

Downstream Products

• 87014-22-0 [1-(3,4-Dimethoxy-phenyl)-4-oxo-cyclohex-2-enyl]-acetic acid; compound with triethyl-amine 
• 21104-34-7 N-methyl-3a-<3,4-(dimethoxy)phenyl>-2,3,3a,4,5,6,7,7a-octahydroindole-2,6-dione 
• 71357-60-3 racemic epijoubertinamine 
• 87014-24-2 4-(3',4'-dimethoxyphenyl)-4-(N-methylcarbonyl)-2-cyclohexenone 
• 87014-23-1 [1-(3,4-Dimethoxy-phenyl)-4-oxo-cyclohex-2-enyl]-acetyl chloride 
• 87014-25-3 2-[1-(3,4-Dimethoxy-phenyl)-4-oxo-cyclohex-2-enyl]-acetamide 
• 34084-31-6 (3aR,7aS)-3a-(3,4-Dimethoxy-phenyl)-2,3,3a,6,7,7a-hexahydro-1H-indol-6-ol 
• 81255-05-2 (+/-)-N-demethylmesembrenone 
• 87014-27-5 2-[1-(3,4-Dimethoxy-phenyl)-4-oxo-cyclohexa-2,5-dienyl]-acetamide 
• 87014-26-4 (3aR,7aR)-3a-(3,4-Dimethoxy-phenyl)-hexahydro-indole-2,6-dione 
• 87039-28-9 (3aS,7aR)-3a-(3,4-Dimethoxy-phenyl)-3,3a,7,7a-tetrahydro-1H-indole-2,6-dione 
• 6023-73-0 mesembrine 

Relevant academic research and scientific papers

Regioselective Arylboration of Isoprene and Its Derivatives by Pd/Cu Cooperative Catalysis

A method for the regioselective arylboration of isoprene and its derivatives is presented. These reactions allow for the synthesis of useful building blocks from simple components. Through these studies, an unusual additive effect with DMAP has been uncovered that allows for altered reactivity and the formation of quaternary carbon centers. The utility of this method is demonstrated toward the formal synthesis of mesembrine.

Allyl vinyl ethers via Wittig olefination: A short and efficient synthesis of (±)-mesembrine

A Wittig olefination-Claisen rearrangement approach has been successfully applied to a short and efficient synthesis of (±)-mesembrine.

A Synthesis of Seco-mesembrane Alkaloids, (+/-)-Joubertiamine, (+/-)-Joubertinamine, and (+/-)-Epijoubertinamine

A synthesis of seco-mesembrane alkaloids, (+/-)-joubertiamine (4), (+/-)-joubertinamine (5), and (+/-)-epijoubertinamine (6), was accomplished starting with 2-allyl-2-aryl-5,5-ethylenedioxycyclohexanones (10 and 3), which are readily available by allylati

Total Syntheses of (+/-)-Mesembrine, (+/-)-Joubertinamine, and (+/-)-N-Demethylmesembrenone

The syntheses of three members of the sceletium alkaloid family are developed from a common synthon, leading to short, high-yielding stereorational routes to (+/-)-mesembrine, (+/-)-joubertinamine, and (+/-)-N-demethylmesembrenone.The latter is synthesize