622852-28-2Relevant academic research and scientific papers
Synthesis of polyfluoroalkyl aza-polycyclic aromatic hydrocarbons enabled by addition of perfluoroalkyl radicals onto vinyl azides
Wang, Yi-Feng,Lonca, Geoffroy Herve,Le Runigo, Maiwenn,Chiba, Shunsuke
, p. 4272 - 4275 (2014)
Radical perfluoroalkylation of α-(biaryl-2-yl)vinyl azides is capable of supplying polyfluoroalkyl aza-polycyclic aromatic hydrocarbons (aza-PAHs). Commercially available Me3SiRf (Rf = CF 3, C2F5
A short access to the skeleton of elisabethin a and formal syntheses of elisapterosin B and colombiasin A
Preindl, Johannes,Leitner, Christian,Baldauf, Simon,Mulzer, Johann
supporting information, p. 4276 - 4279 (2014/11/08)
A short stereoselective synthesis of the Elisabethin A skeleton 4 is described, which opens a formal access to the diterpenes Elisapterosin B and Colombiasin A as well. Key reactions were an intermolecular endo-selective Diels-Alder reaction to generate t
Access to orthogonal protected phenols - Synthesis of a silylated quinol
Siddiqi, Shahzad A.,Heckrodt, Thilo J.
, p. 328 - 331 (2007/10/03)
Herein we describe the synthesis of t-butyldimethylsilyl protected quinol (9), using an oxidation/reduction sequence to create the desired orthogonality. The title compound acts as a synthetic equivalent for a quinone, required in the total synthesis of E
