77803-77-1

Basic information

• Product Name: (1S*,4R*)-4-aminocyclohex-2-enol
• CAS NO: 77803-77-1
• Molecular Weight: 113.159
• Mol File: 77803-77-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1S*,4R*)-4-aminocyclohex-2-enol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S*,4R*)-4-aminocyclohex-2-enol(77803-77-1)
• EPA Substance Registry System: (1S*,4R*)-4-aminocyclohex-2-enol(77803-77-1)

Safety Data

• Hazardous Substances Data: 77803-77-1(Hazardous Substances Data)

Upstream product

• 1165952-91-9 cyclohexa-1,3-diene 
• 237752-48-6 2-oxa-3-azabicyclo[2.2.2]oct-5-en-3-yldiphenylphosphine oxide 
• 56239-25-9 2-Oxa-3-azabicyclo<2.2.2>oct-5-ene hydrochloride 
• 56239-25-9 (+/-)-2-Oxa-3-azabicyclo[2.2.2]oct-5-ene hydrochloride 

Downstream Products

• 131244-18-3 (+/-)-4c-phthalimidocyclohex-2-en-1r-ol 
• 784106-45-2 (+/-)-2c,4c-diaminocyclohexane-1r,3t-diol 
• 73237-85-1 (+/-)-2c,4c-diaminocyclohexan-1r-ol 
• 131244-25-2 (+/-)-3t-iodo-4c-phthalimido-2c-trichloracetamidocyclohexyl acetate 
• 131244-36-5 (+/-)-3t-hydroxy-6t-phthalimido-2t-trichloroacetamidocyclohexyl acetate 
• 131244-27-4 (+/-)-2c-acetamido-4c-phthalimidocyclohexyl acetate 
• 131244-22-9 (+/-)-4c-phthalimidocyclohex-2-enyl trichloroacetimidate 
• 131244-20-7 (+/-)-3r-isopropyldimethylsiloxy-6c-phthalimidocyclohexene 
• 77803-79-3 N-(cis-4-Hydroxy-2-cyclohexen-1-yl)acetamid 
• 77803-78-2 cis-1-Acetamido-2-cyclohexen-4-ylacetat 
• 20021-57-2 r-1-Acetamidocyclohexan-t-2,t-3,c-4-triyltriacetat 
• 77803-85-1 r-1-Acetamido-c-2,c-3-epoxy-c-4-cyclohexylacetat 
• 77803-82-8 c-2-Acetoxy-t-3-brom-c-4-hydroxy-r-1-cyclohexylammoniumbromid 
• 77803-80-6 r-1-Acetamido-t-3-brom-c-2-hydroxy-c-4-cyclohexylacetat 

Relevant articles and documents

Hetero-Diels-Alder reaction of phosphinyl and phosphonyl nitroso alkenes with conjugated dienes: An aza-Cope rearrangement

Phosphorylated nitroso alkenes react with cyclic dienes such as cyclopentadiene or cyclohexadiene to afford hetero Diels-Alder-type cycloadducts where the nitroso alkene participates as dienophile component and the cyclic olefin acts as the 4π-electron (diene) system. Subsequent aza-Cope rearrangement affords highly functionalized 5,6-dihydro-4H-1,2-oxazines. Conversely, the reaction of TMS-substituted cyclopentadiene (dienophile) with nitroso alkenes as heterodienes leads directly to bicyclic 1,2-oxazines. Theoretical studies are in agreement with the experimental results and with the new aza-Cope rearrangement proposed.

THE MICROBIAL REDUCTIVE SPLITTING OF THE N-O BOND OF DIHYDROOXAZINES; AN ALTERNATIVE TO THE CHEMICAL REDUCTION

In the presence of artificial mediators many bacteria reductively split the N-O bond of dihydrooxazines in a chemoselective way if hydrogen is used as an electron source.The yields as determined by HPLC are almost quantitative i.e. considerably better tha