77803-78-2Relevant academic research and scientific papers
THE MICROBIAL REDUCTIVE SPLITTING OF THE N-O BOND OF DIHYDROOXAZINES; AN ALTERNATIVE TO THE CHEMICAL REDUCTION
Klier, K.,Kresze, G.,Werbitzky, O.,Simon, H.
, p. 2677 - 2680 (2007/10/02)
In the presence of artificial mediators many bacteria reductively split the N-O bond of dihydrooxazines in a chemoselective way if hydrogen is used as an electron source.The yields as determined by HPLC are almost quantitative i.e. considerably better tha
Polyhydroxyamino Compounds via Diene Synthesis with Nitroso Compounds, IV. - Preparation and Stereochemistry of Dideoxyinosamine Derivatives
Kresze, Guenter,Kysela, Ernst
, p. 202 - 209 (2007/10/02)
The general method for the synthesis of polyhydroxy amines by Diels-Alder reactions with a nitroso compound, reduction of the adduct with cleavage of the N - O bond and hydroxylation of the remaining C = C -double bond, can also be realized with α-chloronitrosocyclohexane as dienophile, in good yield.Primary amines are synthesized in this way.
