77803-85-1

Upstream product

• 56239-25-9 (+/-)-2-Oxa-3-azabicyclo[2.2.2]oct-5-ene hydrochloride 
• 77803-80-6 r-1-Acetamido-t-3-brom-c-2-hydroxy-c-4-cyclohexylacetat 
• 77803-77-1 (1S*,4R*)-4-aminocyclohex-2-enol 
• 77803-78-2 cis-1-Acetamido-2-cyclohexen-4-ylacetat 
• 108-24-7 acetic anhydride 
• 77803-84-0 N-(c-2,3-Epoxy-c-4-hydroxy-r-1-cyclohexyl)acetamid 

Downstream Products

• 20021-57-2 r-1-Acetamidocyclohexan-c-2,t-3,c-4-triyltriacetat 
• 80178-11-6 r-1-Acetamido-t-3-dimethylamino-c-2,c-4-cyclohexadiyl-diacetat 
• 80178-09-2 r-1,t-2-Diacetamido-c-3,c-4-cyclohexandiyl-diacetat 

Relevant academic research and scientific papers

Polyhydroxyamino Compounds via Diene Synthesis with Nitroso Compounds, IV. - Preparation and Stereochemistry of Dideoxyinosamine Derivatives

The general method for the synthesis of polyhydroxy amines by Diels-Alder reactions with a nitroso compound, reduction of the adduct with cleavage of the N - O bond and hydroxylation of the remaining C = C -double bond, can also be realized with α-chloronitrosocyclohexane as dienophile, in good yield.Primary amines are synthesized in this way.

Polyhydroxyamino Compounds via Diene Synthesis with Nitroso Compounds, VIII. - Preparation of Diamino Derivatives via Epoxides

The epoxidation of the aminocyclohexenols 1 proceeds specifically with syn-attack and formation of the epoxides 2.Reactions of 2 with ammonia or dimethylamine leads to the inosdiamines 3 or 4, respectively.