77815-76-0

Basic information

• Product Name: 1,1-bis(phenylthio)-1-phenylpentane
• Synonyms: 1,1-bis(phenylthio)-1-phenylpentane
• CAS NO: 77815-76-0
• Molecular Weight: 364.576
• Mol File: 77815-76-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,1-bis(phenylthio)-1-phenylpentane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-bis(phenylthio)-1-phenylpentane(77815-76-0)
• EPA Substance Registry System: 1,1-bis(phenylthio)-1-phenylpentane(77815-76-0)

Safety Data

• Hazardous Substances Data: 77815-76-0(Hazardous Substances Data)

Upstream product

• 542-69-8 1-iodo-butane 
• 7695-69-4 bis(phenylthio)methylbenzene 
• 109-65-9 1-bromo-butane 

Downstream Products

• 1009-14-9 phenyl butyl ketone 
• 77815-48-6 1-phenyl-1-phenylthio-1-trimethylsilylpentane 

Relevant articles and documents

Synthesis of Alkenes via Peterson Reaction

The α-phenylthiosilanes (2) have been used to prepare the α-silyl anions (1) by reaction with lithium naphthalenide; subsequent condensation with a carbonyl compound gave the alkene (8) via the Peterson reaction.The α-phenylthiosilanes (2) were prepared from n,n-bis(phenylthio)acetals (4) by reaction with lithium naphthalenide and chlorotrimethylsilane.The n,n-bis(phenylthio)acetals (4) were obtained, in turn, from 1,1-bis(phenylthio)acetals (5) by anion formation with butyl-lithium-N,N,N',N'-tetramethylethylenediamine complex in hexane followed by reaction with an alkyl halide.The Peterson reaction was also used to prepare vinyl sulphides (9) and vinyl sulphones (13).