7787-69-1Relevant articles and documents
Crystal growth and characterization of Eu2+ doped Cs1-xRbxCaBr3
Rebrova,Grippa, A.Yu.,Boiaryntseva,Berastegui,Gorbacheva,Pedash, V.Yu.,Galkin,Kononets,Datsko, Yu.N.,Cherginets
, (2020)
A series of Eu2+ doped Cs1-xRbxCaBr3 solid solutions were grown using the Bridgman-Stockbarger technique. Their photoluminescence and scintillation properties are studied. Upon optical and X-ray excitation, the Cs1-xRbxCaBr3 and Eu2+ activated samples show a band, which can be attributed to the 5d-4f transition in Eu2+. The decay time constants become shorter with increasing Rb content and lie in the range of 3–4 μs. The scintillation performance of solid solutions Cs1-xRbxCa0.95Eu0.05Br3 is improved compared with the end members (CsCa0.95Eu0.05Br3 and RbCa0.95Eu0.05Br3). The best energy resolution of 6.4% at 662 keV was determined for Cs0.2Rb0.8Ca0.95Eu0.05Br3, and the best light yield, equal to 61.2% of NaI:Tl, was demonstrated by Cs0.4Rb0.6Ca0.95Eu0.05Br3.
Hydrothermal Crystal Growth of Mixed Valence Cs2SbBr6
Combs, Victoria E.,Oswald, Iain W. H.,Neilson, James R.
, p. 4090 - 4094 (2019)
Mixed valence perovskite materials present an opportunity to understand how structural motifs influence electronic properties in semiconducting materials. Here, we report the preparation of high-quality single crystals of the mixed valence compound Cssub
Ion Exchange of Layered Alkali Titanates (Na2Ti3O7, K2Ti4O9, and Cs2Ti5O11) with Alkali Halides by the Solid-State Reactions at Room Temperature
Ogawa, Makoto,Saothayanun, Taya Ko,Sirinakorn, Thipwipa Tip
, p. 4024 - 4029 (2020/04/08)
Ion exchange of layered alkali titanates (Na2Ti3O7, K2Ti4O9, and Cs2Ti5O11) with several alkali metal halides surprisingly proceeded in the solid-state at room temperature. The reaction was governed by thermodynamic parameters and was completed within a shorter time when the titanates with a smaller particle size were employed. On the other hand, the required time for the ion exchange was shorter in the cases of Cs2Ti5O11 than those of K2Ti4O9 irrespective of the particle size of the titanates, suggesting faster diffusion of the interlayer cation in the titanate with lower layer charge density.