77896-90-3Relevant academic research and scientific papers
ACYCLIC STEREOCONTROL IN THE ADDITION OF γ-ALKYLTHIO-ALLYLBORONATES TO ALDEHYDES
Hoffmann, Reinhard W.,Kemper, Bruno
, p. 2219 - 2224 (1984)
The Z-isomer 10 of the γ-alkylthio-allylboronates adds to aldehydes giving the syn diastereomer 4 of the product homoallyl-alcohol.The E-isomer 12 leads in turn to the anti-diastereomer 5 with a high degree of acyclic stereocontrol.Kinetic diasteroselecti
