Tetrahedron p. 2219 - 2224 (1984)
Update date:2022-08-05
Topics:
Hoffmann, Reinhard W.
Kemper, Bruno
The Z-isomer 10 of the γ-alkylthio-allylboronates adds to aldehydes giving the syn diastereomer 4 of the product homoallyl-alcohol.The E-isomer 12 leads in turn to the anti-diastereomer 5 with a high degree of acyclic stereocontrol.Kinetic diasteroselecti
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