78135-47-4Relevant articles and documents
Total synthesis of graphislactone G
Cudaj, Judith,Podlech, Joachim
supporting information; experimental part, p. 3092 - 3094 (2010/07/18)
We present a total synthesis of the fungal natural product graphislactone G, a chlorinated resorcylic lactone. The key step is a Suzuki coupling used for the construction of the central biaryl bond. Graphislactone G was prepared in 13 steps with 22% yield
104. Synthese de l'eriodermine
Pulgarin, Cesar,Gunziger, Jan,Tabacchi, Raffaele
, p. 945 - 948 (2007/10/02)
Synthesis of Eriodermin.The total synthesis of eriodermin (=2,7-dichloro-4-formyl 3-hydroxy-8-methoxy-1,6-dimethyl-11H-dibenzodioxepin-11-one) is described.
Depsidone Synthesis. Part 16. Benzophenone-Grisa-3',5'-diene-2',3-dione-depsidone Interconversion: a New Theory of Depsidone Biosynthesis
Sala, Tony,Sargent, Melvyn V.
, p. 855 - 869 (2007/10/02)
The synthesis of a number of grisa-3',5'-diene-2',3-diones by oxidative coupling of substituted 2,2'-dihydroxy-4-methoxybenzophenones is described.The rearrangement of these grisadienediones to depsidones under basic, acidic, and thermal conditions is des