782491-17-2Relevant academic research and scientific papers
Copper-mediated oxidative pentafluoroethylthiolation of aryl boronic acids with TMSC2F5 and elemental sulfur
Xiang, Jia-Xiang,Xu, Xiu-Hua,Qing, Feng-Ling
, p. 110 - 114 (2017/09/06)
A copper-mediated oxidative pentafluoroethylthiolation of aryl boronic acids with TMSC2F5 and S8 was developed. This reaction provides a new access to various aryl pentafluoroethyl thioethers. The use of 2-fluoropyridine as the ligand and the ability to carry out the reaction at 70 °C are key features of this oxidative coupling reaction.
Synthesis of perfluoroalkyl thioethers from aromatic thiocyanates by iron-catalysed decarboxylative perfluoroalkylation
Exner, Benjamin,Bayarmagnai, Bilguun,Matheis, Christian,Goossen, Lukas J.
, p. 89 - 93 (2017/06/23)
Easily available aryl and heteroaryl thiocyanates were converted into the corresponding perfluoroalkyl thioethers via decarboxylation of potassium perfluoroalkylcarboxylates, catalysed by the inexpensive and environmentally benign iron(III) chloride.
PESTICIDAL COMPOSITIONS
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Page/Page column 28, (2011/02/24)
The present invention concerns novel heteroaryl-N-aryl thiosemicarbazones and their use in pest control, as insecticides and acaπcides This invention also includes preparation of the pesticide compositions containing the compounds, and methods of controlling insects using the compounds
PESTICIDAL COMPOSITIONS
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Page/Page column 28, (2011/02/24)
The present invention concerns novel heteroaryl-N-aryl carbamates and their use in pest control, as insecticides and acaricides This invention also includes preparation of the pesticide compositions containing the compounds, and methods of controlling insects using the compounds.
Synthesis of aryl perfluoroalkyl sulfides from aromatic disulfides
Sipyagin,Enshov,Kashtanov,Potemkin,Thrasher,Waterfeld
, p. 420 - 434 (2007/10/03)
Thermolysis of xenon(II) bis(perfluoroalkanecarboxylates) in the presence of diaryl disulfides occurs through the S-S bond cleavage to form dihalo-, halonitro-, and halodinitrophenyl perfluoroalkyl sulfides. The latter type of compounds was obtained for the first time. The main side process is the perfluoroalkylation of the aromatic ring.
Nonlinear Optical Epoxy Polymers with Polar Tolan Chromophores
Twieg, R.,Ebert, M.,Jungbauer, D.,Lux, M.,Reck, B.,et al.
, p. 19 - 24 (2007/10/02)
A variety of optically nonlinear tolan chromophores and epoxy based polymers containing them have been prepared and studied.The molecular hyperpolarizabilities of the dye chromophores have been measured by the EFISH technique while the polymers containing
