78344-00-0Relevant academic research and scientific papers
Syn-Stereocontrolled dihydroxylation of Baylis-Hillman adducts
Marko, Istvan E.,Giles, Paul R.,Janousek, Zdenek,Hindley, Nigel J.,Declercq, Jean-Paul,et al.
, p. 239 - 241 (2007/10/02)
The hydroxylation of Baylis-Hillman adducts 1 is shown to proceed with high levels of diastereocontrol.A mechanistic rationale to explain this selectivity is discussed.
Aldol Reaction of Aluminium Enolate Resulting from 1,4-Addition of R2AlX to α,β-Unsaturated Carbonyl Compound. A 1-Acylethenyl Anion Equivalent
Itoh, Akira,Ozawa, Shuji,Oshima, Koichiro,Nozaki, Hitosi
, p. 274 - 278 (2007/10/02)
Organoaluminium reagents R2AlX (X=SPh, SeMe) easily add to α,β-unsaturated carbonyl compounds in 1,4-fashion.The resulting aluminium enolates react with aldehydes to give aldol adducts in fair to good yields.Formal elimination of HX from the adducts provi
