78426-90-1

Upstream product

• 4994-13-2 4-methylcyclohexanone oxime 
• 75-36-5 acetyl chloride 
• 546-67-8 lead(IV) tetraacetate 
• 589-92-4 1-methylcyclohexan-4-one 
• 18649-43-9 4-methoxyphenyllead(IV) triacetate 
• 5601-45-6 4-(4-methylcyclohex-1-en-1-yl)morpholine 

Downstream Products

• 195435-29-1 2-(2-diethoxyphosphoryl)propionyloxy-4-methylcyclohexanone 
• 195435-28-0 2-(2-chloropropionyloxy)-4-methylcyclohexanone 
• 13341-72-5 menthalactone 
• 118759-44-7 2-hydroxy-4-methylcyclohexanone 

Relevant academic research and scientific papers

A facile synthesis of (±)-mintlactone

(±)-Mintlactone has been synthesized by applying a novel effective synthetic sequence. 4-Methylcyclohexanone was subjected to acetoxylation with Pb(OAc)4. Hydrolysis followed by reaction with 2-chloropropionyl chloride, then treatment with trie

The Chemistry of Aryllead(IV) Tricarboxylates. Reaction with Enamines

The treatment of 1-morhpholinocyclopentene (1a) with p-methoxyphenyllead triacetate (2a) in chloroform provides a simple high-yielding route to 2-(4-methoxyphenyl)cyclopentanone (3a).This arylation reaction of enamines has been investigated with a variety of substrates and a number of aryllead triacetates.The reaction has been found to be very sensitive to steric effects and is thus a useful synthetic method in a relatively small number of cases.Acetoxylation is a major competing reaction with those enamines of cyclic ketones which give a low to moderate yield of arylated product.