78525-33-4

Upstream product

• 4586-59-8 3-hydroxy-2-isopropyl-5-methyl-[1,4]benzoquinone 
• 77-78-1 dimethyl sulfate 
• 135626-41-4 2-isopropyl-4-hydroxy-5-methyl resorcinol dimethyl ether 
• 144707-39-1 1,3-Dimethoxy-4-hydroxy-2-isopropylbenzene 
• 563-63-3 silver(I) acetate 
• 914618-38-5 6-(hydroxymethyl)-3-isopropyl-2,4-dimethoxyphenol 

Relevant academic research and scientific papers

Efficient generation of ortho -quinone methide: Application to the biomimetic syntheses of (±)-schefflone and tocopherol trimers

An efficient method using silver oxide-mediated oxidation for the synthesis of ortho-quinone methides has been developed and applied to the biomimetic syntheses of novel trimeric natural products, (±)-schefflone and tocopherol trimers. Further studies of the critical trimerization as well as substrate scope and limitations are also reported.

Carbon-13 NMR Studies of Benzoquinones

The assignment of all ring carbons of p-benzoquinones derived from perezone and from thymoquinone was completed using gated decoupled spectra.The long range proton-carbon couplings are discussed in terms of the degree of substitution of the quinone ring.The tautomeric interconversion of the two energetically equivalent forms of 2,5-dihydroxy-1,4-benzoquinones has been studied invarious solvents and at several temperatures.