78549-07-2

Upstream product

• 83408-17-7 1-Phenyl-2-((S)-toluene-4-sulfinyl)-2-p-tolylsulfanyl-ethanone 
• 59532-35-3 (+)-(S)-4-Methylphenyl 4-methylphenylthiomethyl sulfoxide 
• 100-52-7 benzaldehyde 
• 83408-17-7 1-Phenyl-2-(toluene-4-sulfinyl)-2-p-tolylsulfanyl-ethanone 
• 67252-09-9 p-tolyl p-tolylthiomethyl sulphoxide lithium salt 
• 83408-17-7 (S)-1-Phenyl-2-((R)-toluene-4-sulfinyl)-2-p-tolylsulfanyl-ethanone 
• 52317-51-8 p-Toluyl-p-toluylthiomethylsulfoxid 
• 98-88-4 benzoyl chloride 

Downstream Products

• 78517-53-0 C₂₃H₂₄O₂S₂ 
• 72538-26-2 C₂₃H₂₄OS₂ 
• 72538-26-2 C₂₃H₂₄OS₂ 
• 78517-51-8 C₂₂H₂₀OS₂ 
• 83461-64-7 (R)-α-acetoxyphenylacetaldehyde 
• 86448-62-6 (+)-1-phenyl-2,2-bis(p-tolylthio)ethanol 
• 1445-91-6 (S)-1-phenylethanol 
• 86448-80-8 Acetic acid (1R,2R)-1-phenyl-2-((S)-toluene-4-sulfinyl)-2-p-tolylsulfanyl-ethyl ester 

Relevant academic research and scientific papers

Asymmetric Synthesis of Protected α-Hydroxyaldehydes via Reduction of α-Arylthio-β-oxosulphoxides

The complex metal hydride reduction of α-arylthio-β-oxosulphoxides to the corresponding alcohols is highly stereospecific.The stereochemical course of the reaction has been determined and a detailed examination of the factors responsible for the stereospe

AN EFFICIENT 1,3-ASYMMETRIC INDUCTION ACCOMPANIED WITH EPIMERIZATION AT THE 2-POSITION. STEREOSELECTIVE REDUCTION OF α-SUBSTITUTED β-KETO SULFOXIDES UNDER BASIC CONDITIONS

An efficient 1,3-asymmetric induction was realized in the reduction of β-keto sulfoxides having various α-substituents with NaBH4 under basic conditions and, by the application of this induction, (R)-α-acetoxyphenylacetaldehyde was synthesized.

Chiral Acyl Anion and Enolonium Ion Equivalents. Asymmetric Synthesis of α-Methoxy-aldehydes

The reaction of the lithium derivative of (+)-(S)-p-tolyl p-tolylthiomethyl sulphoxide with benzaldehyde and phenylacetaldehyde in tetrahydrofuran at -78 deg C gives, after methylation of the hydroxy-group, reduction of the sulphoxide, and h