78602-07-0Relevant academic research and scientific papers
Chemistry of Four-Membered Cyclic Nitrones. 1. Synthesis and Thermal Isomerization of 2,3-Dihydroazete 1-Oxides
Pennings, Marcel L. M.,Reinhoudt, David N.
, p. 1816 - 1823 (2007/10/02)
Nitroalkenes (1) react with ynamines (1-aminoacetylenes, 2) to yield nitrocyclobutenes 3 and four-membered cyclic nitrones (2,3-dihydroazete 1-oxides, 5); in one case the open-chain isomer (4) of a four-membered cyclic nitrone was isolated.Nitrones 5 isom
OXIDATION OF N-HYDROXYAZETIDINES: A NOVEL SYNTHESIS OF N-ACETOXY β-LACTAMS AND FOUR-MEMBERED CYCLIC NITRONES
Pennings, M. L. M.,Reinhoudt, D. N.
, p. 1003 - 1006 (2007/10/02)
The N-hydroxyazetidines 2 and 3 are prepared starting from 2,3-dihydroazete 1-oxides (1a and 1b) by reduction with sodium borohydride and by reaction with a nucleophile, respectively.The N-hydroxyazetidines 2 and 3 can be oxidized with mercury(II)oxide to
