78693-51-3

Usage

InChI:InChI=1/C5H11.3C4H9.Sn/c1-3-5-4-2;3*1-3-4-2;/h1,3-5H2,2H3;3*1,3-4H2,2H3;/rC17H38Sn/c1-5-9-13-17-18(14-10-6-2,15-11-7-3)16-12-8-4/h5-17H2,1-4H3

Upstream product

• 1461-22-9 tributyltin chloride 
• 693-25-4 n-pentylmagnesium bromide 
• 1461-25-2 tetra-n-butyltin(IV) 
• 3765-65-9 tetrapentyltin 
• 628-17-1 amyl iodide 
• 56-35-9 bis(tri-n-butyltin)oxide 
• 994-31-0 chlorotriethylstannane 

Downstream Products

• 1256563-41-3 C₂₁H₂₇NO₂ 

Relevant academic research and scientific papers

Wurtz-type reductive coupling reaction of primary alkyl iodides and haloorganotins in cosolvent/H2O(NH4Cl)/Zn media as a route to mixed alkylstannanes and hexaalkyldistannanes

Mixed tetra-alkylstannanes R3SnR′ (R = Et, n-Pr, n-Bu and R′= Me, Et, n-Pr, n-Bu, n-Pent) and R2SnR′2 (R = n-Bu and R′ = Me, Et, n-Pr, n-Bu) can be easily prepared in a one-pot synthesis via coupling reaction of alkyl iodides R′I with R3SnX (X = Cl, I) and R2SnCl2 compounds in cosolvent-H2O(NH4Cl) medium mediated by zinc dust. Coupling also occurs with (Bu3Sn)2O. It has been verified that reactions are possible only with primary alkyl iodides; with secondary alkyl iodides the coupling reaction fails. When alkyl chlorides and bromides are used ditin compounds are obtained instead of the unsymmetrical tetra-alkylstannanes. This represents a route to hexaalkyldistannanes.

Preparation of benzylstannanes by zinc-mediated coupling of benzyl bromides with organotin derivatives. Physicochemical characterization and crystal structures

Benzyltrialkyl- (1-13) and benzyltriphenylstannanes (16-22) have been easily prepared in a one-pot synthesis via coupling reaction of benzyl bromide derivatives (C6H5CH2Br and XYC6H3CH2Br, X = H, Y = o-, m-, p-CH3, o-, m-, p-F, o-, m-Cl, and p-Br; X = o-F, Y = p-Br) with R3SnCl compounds (R = Et, Pr, Bu, and Ph) in THF/H2O (NH4Cl) medium mediated by zinc powder. Such coupling also occurs with (Bu3Sn)2O. Dibenzyldibutylstannane (15) is prepared by reaction of benzyl bromide with Bu2SnCl2 or (Bu2SnCl)2O, and (2-naphthylmethyl)tributylstannane (14) by reaction of 2-(bromomethyl)naphthalene with Bu3SnCl. 13C-and 119Sn-NMR data are reported for all compounds, and M?ssbauer data for benzyltributylstannanes 10 and 11 and benzyltriphenylstannanes 16-18 and 20-22. The crystal structures of Ph3SnBn, with Bn = o- (17) and m-ClC6H4CH2 (18) and o- (20) and m-FC6H4-CH2 (21) have been determined.

Preparation and properties of unsymmetrical tetraorganotin compounds

Unsymmetrical tetraorganotins, R2R1R2Sn (R=Me, R1=Bu, R2=Pe (Pe=pentyl) or Ph; R=Bu, R1=Pe, R2=Ph or Me; R=Pe, R1=Bu, R2=Me or Ph), BunR4-nSn (n=1-3, R=Me or Pe) and Pe2R2Sn (R=Me or Ph) have been synthesised.Various physical properties, including mass spectra, 1H and 13C NMR spectra, are reported.