78823-32-2Relevant academic research and scientific papers
THERMAL TRANSFORMATIONS OF OXAZOLE ENDOPEROXIDES: REARRANGEMENTS, FRAGMENTATIONS AND METHANOL ADDITIONS
Gollnick, Klaus,Koegler, Sigrid
, p. 1007 - 1010 (2007/10/02)
Oxazole endoperoxides 1 carrying a phenyl group at C-2 rearrange to triacylamines 3; those carrying a hydrogen atom at C-2 undergo a fragmentation into 1:1 mixtures of nitriles (or HCN) 4 and anhydrides 5, whereas methyl substitution at C-2 gives rise to competition between these two modes of reaction.Methanol addition to 1 leads to 4-methoxy-5-hydroperoxides 6 which easily transform into methyl esters 7 and diacylamines 8.
Phase-Managed Organic Synthesis. A New Synthesis of Mixed Formic Anhydrides
Fife, Wilmer K.,Zhang, Zhi-dong
, p. 3744 - 3746 (2007/10/02)
Two new mixed formic anhydrides, cinnamic formic anhydride and formic 4-methoxybenzoic anhydride, can be prepared in high yield ( c.a. 80percent) from equimolar mixtures of sodium formate and the appropriate acid chloride with a solid-phase copolymer of pyridine 1-oxide as catalyst, and they exhibit excellent selectivity as formylating agents of alcohols and amines
Reaction of Diazonium Salts with Transition Metals. 6. Preparation of Mixed Acid Anhydrides from Arenediazonium Salts and Sodium Carboxylates under Palladium(0) Catalysis
Kikukawa, Kiyoshi,Kono, Kiyoshi,Nagira, Kazuhiko,Wada, Fumio,Matsuda, Tsutomu
, p. 4413 - 4416 (2007/10/02)
The palladium(0)-catalyzed reaction of arenediazonium tetrafluoroborates with carbon monoxide and sodium carboxylates in acetonitrile at 25 deg C gave mixed acid anhydrides, ArCOOCOR (Ar = 3-Me-Ph, 4-Me-Ph, 2-MeO-Ph, 4-Br-Ph, 4-I-Ph, 3-NO2-Ph, 4-NO2-Ph, and Ph; R = H, Me, Et, t-Bu, and Ph) in good yields.Homoaromatic acid anhydrides, (ArCO)2O, were obtained by heating of ArCOOCOMe at 100-120 deg C under vacuum.ArCOOCO-t-Bu can be utilized to obtain the corresponding arenecarboxamides by the reaction with some amines.
