79043-43-9Relevant academic research and scientific papers
O,O-Monochelate complexes of silicon and germanium halides: The derivatives of l-mandelic N,N-dimethylamide
Bylikin,Shipov,Kramarova,Negrebetsky,Korlyukov,Baukov,Hursthouse,Male,Bassindale,Taylor
experimental part, p. 244 - 248 (2009/04/12)
Reactions of O-trimethylsilyl-l-mandelic N,N-dimethylamide (1) with tetrachlorosilane and tetrachlorogermane lead to O,O-monochelate complexes, [1-(dimethylcarbamoyl)-1-phenylmethoxy]trichlorosilane (2) and [1-(dimethylcarbamoyl)-1-phenylmethoxy]trichloro
ON CARBONYL PARTICIPATION IN THE SOLVOLYSES OF α-KETO MESYLATES
Creary, Xavier,McDonald, Steven R.,Eggers, Mark D.
, p. 811 - 814 (2007/10/02)
α-amido mesylates generally solvolyze giving α-keto cations, bypassing cyclic ions derived from carbonyl (kΔ) participation.A possible exception is the N,N-dimethylamido mesylate derived from (S)-mandelic acid in trifluoroacetic acid which gives a small amount (9percent) of retained product.
