79157-37-2Relevant academic research and scientific papers
Bisoxazoline-pincer ligated cobalt-catalyzed hydrogenation of alkenes
Ritz, Mikhaila D.,Parsons, Astrid M.,Palermo, Philip N.,Jones, William D.
supporting information, (2020/02/13)
The efficient and atom economical hydrogenation of alkenes using a novel bisoxazoline ligated cobalt complex has been developed. The hydrogenation of a variety of alkenes containing electron neutral and electron-donating groups proceeds in high yield, whi
Regiodivergent DH or HD Addition to Alkenes: Deuterohydrogenation versus Hydrodeuterogenation
Hilt, Gerhard,Li, Luomo
supporting information, (2020/03/03)
The regioselective and regiodivergent addition of H-D to a variety of 1,1-diarylalkenes was realized utilizing selectively deuterated dihydroaromatic compounds, which were generated by cobalt catalysis. The reaction was initiated by catalytic amounts of B
Metal- and Oxidant-Free Alkenyl C?H/Aromatic C?H Cross-Coupling Using Electrochemically Generated Iodosulfonium Ions
Hayashi, Ryutaro,Shimizu, Akihiro,Davies, Jonathan A.,Ishizaki, Yu,Willis, Chris,Yoshida, Jun-ichi
, p. 12891 - 12895 (2018/09/14)
A three-step transformation consisting of 1) addition of electrochemically generated iodosulfonium ions to vinylarenes to give (1-aryl-2-iodoethoxy)sulfonium ions, 2) nucleophilic substitution by subsequently added aromatic compounds to give 1,1-diaryl-2-
Traceless directing group mediated branched selective alkenylation of unbiased arenes
Agasti, Soumitra,Dey, Aniruddha,Maiti, Debabrata
supporting information, p. 12191 - 12194 (2016/10/21)
Owing to the synthetic importance of branched olefinated products, we report palladium catalyzed formation of branched olefins facilitated by a C-H activation based protocol. This involves selective insertion of olefins and subsequent decarboxylation using a completely unbiased benzene ring as the starting precursor. The significance of the protocol has been further highlighted by exhibition of functionality tolerance along with a late-stage modification of the branched olefinated products leading to the formation of other functionalized molecules.
Synthesis of 1,1-diarylethylenes
Chang, Meng-Yang,Huang, Yi-Hsuan,Wang, Heui-Sin
, p. 3022 - 3031 (2016/05/19)
A facile route toward 1,1-diarylethylenes 6 has been developed in good yields via mCPBA-promoted oxidation of β-hydroxysulfides 2, BF3·OEt2-mediated Friedel-Crafts reaction of the resulting β-hydroxysulfoxides 3 with oxygenated benze
Selective one-pot synthesis of various phenols from diarylethanes
Nakamura, Ryota,Obora, Yasushi,Ishii, Yasutaka
supporting information; experimental part, p. 3417 - 3419 (2009/02/05)
Various substituted phenols were selectively synthesized by a one-pot reaction through the NHPI-catalyzed aerobic oxidation of 1,1-diarylethanes followed by treatment with dilute sulfuric acid. The Royal Society of Chemistry.
LATINONE, A PHENANTHRENE-1,4-QUINONE FROM DALBERGIA LATIFOLIA
Criodain, Thurlough O.,O'Sullivan, Michael,Meegan, Mary Jane,Donnelly, Dervilla M. X.
, p. 1089 - 1092 (2007/10/02)
Latinone, a substituted phenanthrene-1,4-quinone was isolated from Dalbergia latifolia.The structure was assigned from spectroscopic measurements and a synthesis was carried out using a Diels-Alder reaction to form the ring structure.Key Word Index- Dalbergia latifolia; Leguminosae; latinone; quinone; phenanthrene-1,4-quinone.
