79309-65-2Relevant academic research and scientific papers
Blue light-promoted photolysis of aryldiazoacetates
Jurberg, Igor D.,Davies, Huw M. L.
, p. 5112 - 5118 (2018/06/12)
Aryldiazoacetates can undergo photolysis under blue light irradiation (460-490 nm) at room temperature and under air in the presence of numerous trapping agents, such as styrene, carboxylic acids, amines, alkanes and arenes, thus providing a straighforward and general platform for their mild functionalization.
Divergent Roles of Urea and Phosphoric Acid Derived Catalysts in Reactions of Diazo Compounds
Bernardim, Barbara,Couch, Erica D.,Hardman-Baldwin, Andrea M.,Burtoloso, Antonio C. B.,Mattson, Anita E.
, p. 677 - 686 (2016/02/27)
Hydrogen-bond-donor catalysts enable a variety of formal insertion reactions of diazo compounds. The role of the catalyst in the reaction system may vary depending on several factors, including the nucleophilicity of the diazo compound and the acidity of the insertion partner. Ureas and phosphoric acid derivatives can offer complementary reactivity patterns when selected as catalysts for selected O-H and S-H insertion reactions of aryl- and diazo-substituted esters.
HYPERVALENT IODINE IN ORGANIC SYNTHESIS. A NEW ROUTE TO α-FUNCTIONALIZED CARBOXYLATE ESTERS.
Moriarty, Robert M.,Hu, Henry
, p. 2747 - 2750 (2007/10/02)
Aryl and alkylcarboxylate esters are converted into the corresponding α-hydroxy acids or α-alkoxyesters upon treatment with C6H5I(OAc)2 and base in the appropriate solvent.
