79407-40-2

Basic information

• Product Name: 2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane
• Synonyms: 2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane
• CAS NO: 79407-40-2
• Molecular Weight: 254.329
• Mol File: 79407-40-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane(79407-40-2)
• EPA Substance Registry System: 2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane(79407-40-2)

Safety Data

• Hazardous Substances Data: 79407-40-2(Hazardous Substances Data)

Upstream product

• 61440-45-7 3-[4-(benzyloxy)phenyl]propan-1-ol 
• 134721-17-8 1-(benzyloxy)-4-(but-3-en-1-yl)benzene 
• 4397-53-9 p-benzyloxybenzaldehyde 
• 1774-47-6 trimethylsulfoxonium iodide 
• 68486-77-1 3-(4-(benzyloxy)phenyl)propanal 
• 10210-17-0 3-(4-hydroxyphenyl)propan-1-ol 
• 100-39-0 benzyl bromide 
• 123-08-0 4-hydroxy-benzaldehyde 
• 6272-45-3 4-benzyloxycinnamic acid 
• 186895-45-4 ethyl 3-(4-(benzyloxy)phenyl)propanoate 
• 87030-11-3 ethyl 3-(4-(benzyloxy)phenyl)acrylate 

Downstream Products

• 1251830-59-7 4,4'-[(1E,5R)-5-hydroxyhept-1-ene-1,7-diyl]diphenol 
• 1401711-90-7 4-{(1E,5R)-7-[4-(benzyloxy)phenyl]-5-hydroxyhept-1-en-1-yl}phenol 
• 1401711-88-3 (3R)-1-[4-(benzyloxy)phenyl]hept-6-en-3-ol 
• 1010127-34-0 (2S)-2-{2-[4-(benzyloxy)phenyl]ethyl}oxirane 
• 1010127-36-2 C₁₉H₂₀O₂ 

Relevant articles and documents

Catalytic δ-hydroxyalkynone rearrangement in the stereoselective total synthesis of centrolobine, engelheptanoxides A and C and analogues

A catalytic stereoselective total synthesis of centrolobine and engelheptanoxides A and C has been completed via a metal-free catalytic δ-hydroxyalkynone rearrangement to 2,3-dihydro-4H-pyran-4-one and diastereoselective hydrogenation to the all syn-2,4,6-trisubstituted pyran strategy. The onliest required chirality was introduced by Jacobsen kinetic resolution, which further directed the diastereoselective hydrogenation. A first stereoselective synthesis of engelheptanoxide A is also accomplished. The analogues and derivatives of centrolobine and engelheptanoxides prepared were evaluated for antitubercular activity against M. tuberculosis H37Rv ATCC 27294.

The first stereoselective total synthesis of a naturally occurring bioactive diarylheptanoid, (3R,6E)-1,7-bis(4-hydroxyphenyl)hept-6-en-3-ol, through two different approaches

The stereoselective total synthesis of a naturally occurring bioactive diarylheptanoid, (3R,6E)-1,7-bis(4-hydroxyphenyl)hept-6-en-3-ol, has been accomplished starting from 4-hydroxybenzaldehyde through two different approaches involving Wittig olefination